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The Center for Anthropocene Studies (CAS) Opens
KAIST will start Anthropocene research, a convergence field of study, to address issues related to the commencement of human activities that have had scientific, industrial, and economic impacts on the Earth’s ecosystem. The National Research Foundation (NRF) of Korea endorsed the KAIST Center for Anthropocene Studies as its Convergence Research Center project.
Anthropocene refers to a new geological age in which various polluting materials that humans have made during the post-industrial revolution era have made a significant impact on the Earth and the lives of humankind. The studies expand the diverse socio-economic and environmental sectors for responding to climate change, natural disasters, ecological destruction, the polarization of the inequality and wealth, and many others.
The KAIST research group at the center, in collaboration with the Graduate School of Science and Technology Policy, the Graduate School of Culture Technology, the School of Humanities & Social Sciences, the Department of Industrial Design, the School of Electrical Engineering, the Satellite Technology Research Center (SaRTec), and the KAIST Initiative for Disaster Studies will conduct multidisciplinary research to address intriguing challenges with complex but creative approaches incorporating the fields of engineering, socioeconomics, and art.
The group will investigate topics such as▲ surface and marine changes to the Earth by applying satellite data ▲disaster prediction and governance system building through AI modeling ▲sustainable housing, transportation, and lifestyles ▲ engineering and artistic approaches for envisioning a new future for humankind and the Earth.
Professor Buhm Soon Park, who is in charge of the center, said, “This pioneering research work will inspire the re-creation of a new paradigm of convergence studies in science, engineering, humanities, and social science. We will contribute to making the world better by designing new technologies and social policies.
2018.06.05 View 9761 -
Professor YongKeun Park Wins the 2018 Fumio Okano Award
(Professor Park)
Professor YongKeun Park from the Department of Physics won the 2018 Fumio Okano Award in recognition of his contributions to 3D display technology development during the annual conference of the International Society for Optics and Photonics (SPIE) held last month in Orlando, Florida in the US.
The Fumio Okano Best 3D Paper Prize is presented annually in memory of Dr. Fumio Okano, a pioneer and innovator of 3D displays who passed away in 2013, for his contributions to the field of 3D TVs and displays. The award is sponsored by NHK-ES.
Professor Park and his team are developing novel technology for measuring and visualizing 3D images by applying random light scattering. He has published numerous papers on 3D holographic camera technology and 3000x enhanced performance of 3D holographic displays in renowned international journals such as Nature Photonics, Nature Communications, and Science Advances. His technology has drawn international attention from renowned media outlets including Newsweek and Forbes.
He has established two startups to commercialize his technology. Tomocube specializes in 3D imaging microscopes using holotomographic technology and the company exports their products to several countries including the US and Japan. The.Wave.Talk is exploring technology for examining pre-existing bacteria anywhere and anytime.
Professor Park’s innovations have already been recognized in and out of KAIST. In February, he was selected as the KAISTian of the Year for his outstanding research, commercialization, and startups. He was also decorated with the National Science Award in April by the Ministry of Science and ICT and the Hong Jin-Ki Innovation Award later in May by the Yumin Cultural Foundation.
Professor Park said, “3D holography is emerging as a significant technology with growing potential and positive impacts on our daily lives. However, the current technology lags far behind the levels displayed in SF movies. We will do our utmost to reach this level with more commercialization."
2018.05.31 View 8973 -
Fast-Charging Lithium-Oxygen Batteries
(Professor Hye Ryung Byon)
KAIST researchers have paved the way for fast-charging lithium-oxygen batteries.
Professor Hye Ryung Byon from the Department of Chemistry and Professor Yousung Jung from the Graduate School of EEWS led a joint research team to develop lithium-oxygen batteries exhibiting 80% round-trip efficiency even at high charging rates, solving the problem of existing lithium-oxygen batteries which generally showed drastically lower efficiencies when the charge current rate was increased.
This study exploits the size and shape lithium peroxide, a discharge product, which is known to cause the very problems mentioned above. In doing so, the researchers have lowered the overpotential, which is the difference between the thermodynamic reversible potential and the measured potential, and simultaneously improved battery efficiency. Of particular interest is the fact that these high-performance lithium-oxygen batteries can be realized without costly catalysts.
One remarkable property of lithium-oxygen batteries is that they can accommodate three to five times the energy density of lithium-ion batteries commonly used today. Therefore, lithium-oxygen batteries would render longer driving distance to electric vehicles or drones, which operate on the continued use of electrical power.
However, their weakness lies in that, during charge, the lithium peroxide remains undecomposed at low overpotential, resulting in eventually compromising the battery’s overall performance. This is due to the poor ionic and electrical conductivity of lithium peroxide.
To tackle this issue, the researchers could form one-dimensional amorphous lithium peroxide nanostructures through the use of a mesoporous carbon electrode, CMK-3. When compared against non-mesoporous electrodes, CMK-3 showed exceptionally lower overpotential, thereby enhancing the round-trip efficiency of lithium-oxygen batteries.
The amorphous lithium peroxide produced along the electrode has a small volume and a large surface area contacting electrolyte solution, which is presumably endowed with high conductivity to speed up the charging of the lithium-oxygen batteries.
This research underpins the feasibility of overcoming the fundamental limitations of lithium-oxygen batteries even without the addition of expensive catalytic materials, but rather by the re-configuration of the size and shape of the lithium peroxide.
The findings of this research were published in Nature Communications on February 14.
Figure 1. Transmission electron microscopy (TEM) images
Figure 2. Galvanostatic rate capability
Figure 3. Density functional calculation and Bader charge analysis
2018.05.30 View 8885 -
ICISTS 2018: Presence of the Wall, Constraint or Control
A KAIST undergraduates body, ICISTS (International Conference for Integration of Science, Technology and Society) will host the 2018 international conference from July 30 to August 3 at KAIST. Under the theme of “Presence of the Wall: Constraint or Control,” participants will share their opinions on the limits the global world is facing today and look for answers discussing various social issues and technologies. More than 300 students from 60 universities in 15 countries will attend the conference.
Speakers include CEO Sebastien Gendron of TransPod Inc., a Canadian company designing and manufacturing ultra-high-speed transportation technology and vehicles, researcher Sven Kreiss from the Visual Intelligence for Transportation of École Polytechnique Fédérale de Lausanne, Professor Des Freedman from the Department of Media and Communications of Goldsmiths, University of London and political scientist-technologist Wilneida Negrón at the Data & Society Research Institute of Ford Foundation in the US.
The conference will hold programs to facilitate the exchange of ideas among speakers and participants. Participants will make small teams for free discussions to share their ideas and thoughts about issues affecting the human race. Participants will be also assigned a team project in which they must come up with creative ideas based on the lectures. Moreover, they can try new gadgets from companies during the Experience Session.
ICISTS was established in 2005 by undergraduate students from KAIST. The organization holds an international conference every year to explore ways to create harmonization among society, science, and technology. It has grown to become Asia’s largest international student conference.
For learn more and register for the program, please visit http://www.icist.org
2018.05.30 View 5923 -
KAIST Class of '78 Celebrates 40-Year Reunion
(from left: Chairman Hyung Kyu Lim from the KAIST Alumni Scholarship Foundation and KAIST President Sung-Chul Shin)
The Class of 1978 reunited on May 26 at the College of Business on the KAIST Seoul Campus, which was the main campus when they were students 40 years ago. Now leaders of Korea in the sectors of industry, academia, and research, the Class of ’78 held a homecoming event in celebration of the 40th anniversary of their graduation.
Approximately 120 guests attended the event, including the head of the KAIST Alumni Association Ki-Chul Cha, Emeritus Professor Jae-Kyoon Kim, and Emeritus Professor Choong-Ki Kim from the School of Electrical Engineering.
The Class of ’78 includes Man Gi Paik from the Ministry of Trade, Industry and Energy, Chairman Hyung Kyu Lim from the KAIST Alumni Scholarship Foundation, President Sang Hyuk Son from Daegu Gyeongbuk Institute of Science & Technology, and Provost and Executive Vice President O Ok Park from KAIST.
At the event, the Class of ‘78 donated a scholarship worth 1.5 billion KRW. Chairman Lim said, “We will put every effort into helping KAIST students who will be future leaders. We hope this fund will go toward students who will create new value and contribute to society.”
President Shin added, “The effort and affection of the alumni will be a strong foundation for KAIST taking the next big step. In response to the support and affection of 61,125 KAIST alumni, KAIST will make every effort to become a world-leading university.”
2018.05.30 View 4722 -
KAIST-Developed LPV to Launch in LNG-Fueled Port Cleaning Ship in Ulsan
(From left:CEO of LATTICE Technology Kun-Oh Park, research fellow Hwa-Ryong Yu, and Professor Chang )
A KAIST-developed Lattice Pressure Vessel (LPV) will launch inside a 150-ton class port cleaning ship that the Ulsan Port Authority will deploy in December. The ship will operate off the coast of Ulsan and will be the first LNG-fueled public service vessel run by the government.
LATTICE Technology, a tech-startup established in 2012 by two KAIST professors, announced last week that the company signed a contract with the Ulsan Port Authority to install the LPV into the hull of the port cleaning ship.
The company setup by Professors Daejun Chang and Pål G. Bergan in the Department of Mechanical Engineering accomplished the feat seven years after they first registered their original technology patent.
The free-shaped pressure vessel developed by the two professors is applicable to any type of ship structure, a technological breakthrough addressing the wasted installing space of the conventional pressure vessel types that either spherical or cylindrical designs would result in.
The LPV has an internal lattice structure for load carrying caused by pressure, providing 50 percent more capacity than that of a cylindrical pressure vessel.
According to Professor Chang, the essence of the LPV is an internal, modular structure that carries the load by balancing the pressure on opposite walls. He said that the LPV has a number of merits thanks to the lattice structure. While its structural redundancy improves safety, it is fully scalable in any direction as well as being able to mitigate the sloshing load, resulting in a negligible level of fatigue risk. Its modularity also cuts the production cost. The technology has already earned seven internationally authorized certificates, and the company has already built four prototype tanks.
The LPV has significant market potential in the energy storage industry, especially transportation sectors. One imminent application is LNG fuel storage on ships. This cryogenic fuel is expected to replace the conventional marine fuel or heavy fuel oil that is the source of a number of polluting emissions (SOx, NOx, CO2, and particle matters).
This LPV technology will contribute to the efficient storage LNG in volume. As liquid hydrogen increasingly emerges to decarbonate the energy mix, the storage and transportation of liquid hydrogen will be also a critical issue. The researchers expect that this LPV technology will be further applied into the entire supply chain of various fields including production, transportation, storage, and utilization of such decarbonated energy sources.
Professor Chang said, “Pressure vessels are one of the most common devices for storing materials and energy. The areas for which the LPV can create value will expand into various industrial sectors.”
The research team plans to conduct further research and development to realize various LPV applications to store LNG, LPG, liquid hydrogen, carbon dioxide, and steam for ships, land facilities, vehicles, trains, and automobiles.
Figure 1: The internal strucutre of a lattice pressure vessel. The middle part of the tank is repetition of a modular lattice strucutre while the end part is specially designed.
Figure 2: Lattice pressure vessels in shapes and sizes. Unlike conventional cylinders, the lattice pressure vessel can freely assume different shapes and be scaled up through the repetition of modular internal units.
Figure 3: A cylinder tank of 24 m3 and a lattice pressure vessel of 22 m3. They are similar in volume but show a big difference in installation space.
Figure 4: LNF-fueld cruised ships with six cylinders and one lattice pressure vessel. Thanks to its high-volume efficiency, the lattice pressure vessel doubles the stroage volume with one sixth of the piping, instruments, and operational complexity.
2018.05.30 View 7453 -
2018 KAIST Research Day Honors Outstanding Research Achievements
(KAIST President Sung-Chul Shin and Professor Jong-Hwan Kim) Professor Jong-Hwan Kim from the School of Electrical Engineering was recognized at the 2018 KAIST Research Day as the Research Grand Prize Awardee. The ten most distinguished research achievements of the past year were also recognized.
The Research Grand Prize recognizes the professor whose comprehensive research performance evaluation indicator was the highest over the past five years. The indicator combines the number of research contracts, IPR and royalty income.
During the May 25th ceremony, Professor Hyochoong Bang from the Department of Aerospace Engineering and Professor In so Kweon from the School of Electrical Engineering also won the Best Research Award prize.
This year, the Research Innovation Award went to Professor Dong Soo Han from the School of Computing. The Research Innovation Award combines scores in the categories of foreign patent registrations, contracts of technological transfer, and income from technology fees, technology consultations, and startups.
The Convergence Research Award was given to Professor Junmo Kim from the School of Electrical Engineering and Professor Hyun Myung from the Department of Civil & Environmental Engineering. The Convergence Research Award recognizes the most outstanding research team that created innovative research results over a one-year period.
President Sung-Chul Shin said, “KAIST has selected the ten most outstanding research achievements of 2017 conducted by our faculty and researchers. All of them demonstrated exceptional creativity, which opens new research paths in each field though their novelty, innovation, and impact.”
KAIST hosts Research Day every year to introduce major research performances at KAIST and share knowledge about the research and development.
During Research Day, KAIST also announced the ten most distinguished research achievements contributed by KAIST professors during the previous year. They are listed below.
▲ High-Speed Motion Core Technology for Magnetic Memory by Professor Kab-Jin Kim from the Department of Physics
▲ A Double Well Potential System by Professor Jaeyoung Byeon from the Department of Mathematical Sciences
▲ Cheap and Efficient Dehydrogenation of Alkanes by Professor Mu-Hyun Baik from the Department of Chemistry
▲ A Dynamic LPS Transfer Mechanism for Innate Immune Activation by Professor Ho Min Kim from the Graduate School of Medical Science and Engineering
▲ A Memristive Functional Device and Circuit on Fabric for Fibertronics by Professor Yang-Kyu Choi and Professor Sung-Yool Choi from the School of Electrical Engineering
▲ A Hippocampal Morphology Study Based on a Progressive Template Deformable Model by Professor Jinah Park from the School of Computing
▲ The Development of a 6-DOF Dynamic Response Measurement System for Civil Infrastructure Monitoring by Professor Hoon Sohn from the Department of Civil and Environmental Engineering
▲ Cooperative Tumour Cell Membrane Targeted Phototherapy by Professor Ji-Ho Park from the Department of Bio and Brain Engineering
▲ HUMICOTTA: A 3D-Printed Terracotta Humidifier by Professor Sangmin Bae from the Department of Industrial Design
▲ Ultrathin, Cross-Linked Ionic Polymer Thin Films by Professor Sung Gap Im from the Department of Chemical and Biomolecular Engineering
2018.05.28 View 9299 -
Get Treatment Anywhere and Any Time with Wearable PBM Patch
(PhD Candidate Yongmin Jeon)
There have been many cases in which OLEDs are applied to electronic devices, and now they have even been extended to therapeutic fields. A KAIST research team succeeded in developing a wearable photobiomodulation (PBM) patch to treat wounds. This technology will allow injuries to be treated regardless of location or time.
Professor KyungCheol Choi from the School of Electrical Engineering, in collaboration with Seoul National University Bundang Hospital’s team, conducted research on PBMs which are a clinical method widely used in hospitals. They are considered to be a safe, noninvasive, and nonsurgical method that require relatively low light power.
Conventionally, light-emitting diodes (LEDs) have been used in PBM applications; however, LED devices are usually inflexible and difficult to irradiate light uniformly. They may also produce localized heat. Due to these constraints, it was difficult to enhance the clinical effects of LED devices as they cannot stick to the human body.
Choi’s team developed a wearable patch using flexible OLEDs, allowing people to be treated outside of hospitals. A thin film has been developed for the patch, containing not only flexible OLEDs but also batteries and anti-superheating devices.
Moreover, its thickness is less than 1mm and its weight is less than 1g. This lightweight and ultra-thin patch with a bending radius is 20mm can be used more than 300 hours.
These patches are usable at a temperature below 42℃ to eliminate the risk of low-temperature burns. They also meet the safety regulations of the International Organization for Standardization (ISO) at red wavelengths (600–700 nm).
The wearable PBM patches showed excellent effects with in vitro wounds because they stimulated cell proliferation over 58% of control as well as cell migration over 46% of control under various conditions.
Yongmin Jeon, who led this research, said, “The wearable PBM is effective and convenient, so people can simply purchase it at a pharmacy without having to visit a hospital. If we can adjust the power and wavelength of the OLEDs, its application can be extended to skin care, cancer treatment, Alzheimer’s disease treatment, and mental healthcare.”
Professor Choi added, “We have applied the advantages of flexible OLEDs, which are often used for fabricating displays, to PBMs. This technology will open the way to commercialize portable and highly-efficient wearable photobiomodulation devices.”
This research was published in the front cover of Advanced Materials Technologies on May, 2018.
Figure 1. The patch attached to a human face, a hand and examples of treatment applications
Figure 2. The migration of cells into the scratched area
2018.05.25 View 7012 -
Recombinant E. Coli As a Biofactory for the Biosynthesis of Diverse Nanomaterials
(Distinguished Professor Lee and PhD candidate Choi)
A metabolic research group at KAIST and Chung-Ang University in Korea has developed a recombinant E. coli strain that biosynthesizes 60 different nanomaterials covering 35 elements on the periodic table. Among the elements, the team could biosynthesize 33 novel nanomaterials for the first time, advancing the forward design of nanomaterials through the biosynthesis of various single and multi-elements.
The study analyzed the nanomaterial biosynthesis conditions using a Pourbaix diagram to predict the producibility and crystallinity. Researchers studied a Pourbaix diagram to predict the stable chemical species of each element for nanomaterial biosynthesis at varying levels of reduction potential (Eh) and pH. Based on the Pourbaix diagram analyses, the initial pH of the reaction was changed from 6.5 to 7.5, resulting in the biosynthesis of various crystalline nanomaterials that were previously amorphous or not synthesized.
This strategy was extended to biosynthesize multi-element nanomaterials. Various single and multi-element nanomaterials biosynthesized in this research can potentially serve as new and novel nanomaterials for industrial applications such as catalysts, chemical sensors, biosensors, bioimaging, drug delivery, and cancer therapy.
A research group consisting of PhD candidate Yoojin Choi, Associate Professor Doh Chang Lee, and Distinguished Professor Sang Yup Lee of the Department of Chemical and Biomolecular Engineering at KAIST and Associate Professor Tae Jung Park of the Department of Chemistry at Chung-Ang University reported the synthesis. This study, entitled “Recombinant Escherichia coli as a biofactory for various single- and multi-element nanomaterials,” was published online in the Proceedings of the National Academy of Sciences of the United States of America (PNAS) on May 21.
A recent successful biosynthesis of nanomaterials under mild conditions without requiring physical and chemical treatments has triggered the exploration of the full biosynthesis capacity of a biological system for producing a diverse range of nanomaterials as well as for understanding biosynthesis mechanisms for crystalline versus amorphous nanomaterials.
There has been increased interest in synthesizing various nanomaterials that have not yet been synthesized for various applications including semiconducting materials, enhanced solar cells, biomedical materials, and many others. This research reports the construction of a recombinant E. coli strain that co-expresses metallothionein, a metal binding protein, and phytochelatin synthase that synthesizes the metal-binding peptide phytochelatin for the biosynthesis of various nanomaterials. Subsequently, an E. coli strain was engineered to produce a diverse range of nanomaterials, including those never biosynthesized before, by using 35 individual elements from the periodic table and also by combining multi-elements.
Distinguished Professor Lee said, “An environmentally-friendly and sustainable process is of much interest for producing nanomaterials by not only chemical and physical methods but biological synthesis. Moreover, there has been much attention paid to producing diverse and novel nanomaterials for new industrial applications. This is the first report to predict the biosynthesis of various nanomaterials, by far the largest number of various single- and multi-elements nanomaterials. The strategies used for nanomaterial biosynthesis in this research will be useful for further diversifying the portfolio of nanomaterials that can be manufactured.”
Figure: The biosynthesis of diverse nanomaterials using recombinant E. coli. This schematic diagram shows the overall conceptualization of the biosynthesis of various single and multi-element nanomaterials using recombinant E. coli under incubation with corresponding elemental precursors. The 35 elements that were tested to biosynthesize nanomaterials are shown in black circles on the periodic table.
2018.05.23 View 10309 -
A High-Performance and Cost Effective Hydrogen Sensor
(Research team of Professor Park, Professor Jung, and research fellow Gao Min)
A KAIST research team reported a high-performance and cost effective hydrogen sensor using novel fabrication process based on the combination of polystyrene nanosphere lithography and semiconductor microfabrication processes.
The research team, led by Professor Inkyu Park in the Department of Mechanical Engineering and Professor Yeon Sik Jung in the Department of Materials Science and Engineering, fabricated a nanostructured high-performance hydrogen gas sensor based on a palladium-decorated silicon nanomesh structure made using a polystyrene nanosphere self-assembly method. Their study was featured as the front cover article of journal “Small” (Publisher: Wiley-VCH) on March 8, 2018.
The nanosphere lithography method utilizes the self-assembly of a nanosphere monolayer. This could be an alternative choice for achieving uniform and well-ordered nanopatterns with minimum sub-10 nanometer dimensions. The research team said that the small dimensions of the silicon enhanced the palladium-gating effect and thus dramatically improved the sensitivity.
Hydrogen gas is widely considered to be one of the most promising next-generation energy resources. Also, it is a very important material for various industrial applications such as hydrogen-cooled systems, petroleum refinement, and metallurgical processes. However, hydrogen, which is highly flammable, is colorless and odorless and thus difficult to detect with human senses. Therefore, developing hydrogen gas sensors with high sensitivity, fast response, high selectivity, and good stability is of significant importance for the rising hydrogen economy.
Silicon nanowire-based devices have been employed as efficient components in high-performance sensors for detecting gases and other chemical and biological components. Since the nanowires have a high surface-to-volume ratio, they respond more sensitively to the surrounding environment.
The research team’s gas sensor shows dramatically improved hydrogen gas sensitivity compared with a silicon thin film sensor without nanopatterns. Furthermore, a buffered oxide etchant (BOE) treatment of the silicon nanomesh structure results in an additional performance improvement through suspension of nanomesh strutures from the substrate and surface roughening. The sensor device shows a fast hydrogen response (response time < 5 seconds) and 10 times higher selectivity to hydrogen gas among other gases. Their sensing performance is stable and shows repeatable responses in both dry and high-humidity ambient environments.
Professor Park said that his approach will be very useful for the fabrication of low-cost, high-performance sensors for chemical and biological detection with applications to mobile and wearable devices in the coming era of internet of things (IoTs).
(Figure 1: The front cover image of Small dated on March 8.)
(Figure 2: Gas sensor responses upon the exposure to H2 at various concentrations.)
2018.05.21 View 8579 -
Platinum Catalyst Has Price Lowed and Durability Doubled
(Professor Cho in the Department of Materials Science and Engineering)
Professor EunAe Cho in the Department of Materials Science and Engineering reported a fuel cell catalyst that shows 12 times higher performance and twice the durability than previously used platinum catalyst.
Fuel cells, eco-friendly power generators, are said to be running air purifiers. A hydrogen vehicle powered by fuel cells can allegedly purify more than 98 percent of the particulate matter and ultrafine particles from the amount of air that 70 adults breathe.
Despite this peculiarity, the high price of platinum, which is used as an electrode catalyst, remains a big challenge to accelerating commercialization. In addition, recently developed ‘nano-structured platinum catalysts’ have not yet commercialized due to its meager oxygen reduction reaction and durability in fuel cell.
Addressing all those challenges, Professor Cho’s team reported a platinum catalyst costing 30 percent less but boasting 12 times higher performance.
The research team, to this end, combined the platinum with nickel, then applied various metallic elements for making the most efficient performance. Among others, they found that the addition of gallium can modulate the oxygen intermediate binding energy, leading to enhanced catalytic activity of the oxygen reduction reaction.
They made octahedron nanoparticle platinum-nickel alloy and could efficiently achieve 12-times high performance with the platinum catalyst by adding gallium to the surface of octahedron.
Existing fuel cell catalysts have issues in practical fuel cell applications. However, Professor Cho’s team experimentally proved the high performance of the catalyst even in the fuel cell, and is expected to be practically applied to the existing procedure.
First author JeongHoon Lim said their work demonstrates the gallium-added octahedral nanoparticles can be utilized as a highly active and durable oxygen reduction reaction catalyst in practical fuel cell applications. It will make it feasible for the mass production of the catalysts.
Professor Cho also said, “Our study realized the two main goals: an affordable price and increased performance of fuel cells. We hope this will make a contribution to the market competitiveness of fuel cell electric vehicles.”
This research was described in Nano Letters in April and was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP), the National Research Foundation (NRF), and the Agency for Defense Development (ADD).
(Figure: HAADF STEM images with EDX analyses and line scanning profiles of (a) Ga-PtNi/C and (b) PtNi/C during the voltage-cycling tests. The composition changes of Ni, Pt, and Ga atoms in the nanoparticles were determined by EDX (inset in the EDX mapping results)).
2018.05.15 View 6846 -
Capillary Forces at Work for Lithium-Sulfur Batteries
Professor Do Kyung Kim from the KAIST Department of Materials Science and Engineering and his team succeeded in developing high-areal-capacity lithium sulfur batteries (Li-S batteries) by capturing polysulfide with carbon nanofibers. This research will provide new batteries to replace existing lithium rechargeable batteries, shifting the commercialization of related technologies ahead.
Electrical vehicles and large-scale energy storage systems necessitate the development of batteries with high energy density and cost effectiveness, and Li-S batteries are known to be one of the promising alternatives to the predominant lithium ion batteries.
With six times as much energy density, Li-S batteries theoretically thrust electric vehicle to twice the distance of lithium ion batteries. Therefore, they have been spotlighted as next-generation lithium rechargeable batteries because they can go up to 400km once charged.
However, several issues make it challenging to readily commercialize Li-S batteries. The low electrical conductivity of sulfur, volumetric expansion and contraction of the battery during charge and discharge, and permanent damage of the electrode caused by the dissolution of the lithium polysulfide into the electrolyte – known as the “shuttle effect” – are three of the biggest obstacles to commercial-grade Li-S batteries.
While there have been numerous attempts to curb, avoid, or alleviate these issues — such as the physical encapsulation of sulfur using various metal oxides or carbonaceous matrices — most of them entail utilizing zero-dimensional (0D) carbon materials. This encapsulation method has been somewhat effective in enhancing the electrical conductivity of sulfur while simultaneously tolerating some volumetric alterations and suppressing the shuttle effect. The downside of 0D carbon material-based encapsulation methods is their complicated synthetic processing and the limited mass loading of sulfur.
With this in mind, the team set out to employ one-dimensional (1D) carbon materials instead. Unlike the 0D case, 1D carbon materials render a large surface area and a long-range conduction path for electrons and lithium ions. Being 1D also solves the undesirable high-contact resistance problem frequently encountered by 0D carbon material-based encapsulation.
The key to developing the proposed material was to exploit the capillary force to decrease the energy associated with the dissolution of polysulfides. As such, carbon nanofibers (CNFs) were found to be suitable for high-areal-capacity lithium-sulfur batteries since capillary force acting between CNFs can take advantage of the high electrical conductivity with the suppressed dissolution of sulfides.
The research findings show that sulfur was successfully contained in between the CNFs by wetting due to the capillary force without the need for complicated synthetic processing, as in the 0D case. The research results indicate that the sulfur contained per unit area (mg/cm2) is five times greater for the newly implemented method, which then enabled the lithium-sulfur battery to achieve an areal capacity of 7 mAh/cm2, which amounts to as much as at most seven times that of conventional lithium ion batteries.
First author Jong Hyuk Yun stated that the unprecedented methods utilized in this study will help further and widen the progress of lithium batteries in general. Meanwhile, Professor Kim said, “This study brought us closer to commercial-grade high-capacity Li-S batteries, which are applicable for a wide variety of products, including electric vehicles, unmanned aerial vehicles (UAVs), and drones.”
This research, led by PhD candidate Yun, was published in the 18th issue of this year’s Nano Letters.
Figure 1. Electrochemical reaction leading to the containment of the sulfur within the carbon nanofiber and the corresponding specific capacity of the battery over a number of charge-discharge cycles
Figure 2. SEM images of the first discharged electrode containing lithium sulfide at the junction between the nanofibers, and the first charged electrode
Figure 3. carbon nanofiber effectively absorbing liquid based lithium polysulfide
2018.05.14 View 7233