Byeong-Soo+Bae
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KAIST Develops Stretchable Displays Featuring 25% Expansion Without Image Distortion
Stretchable displays, praised for their spatial efficiency, design flexibility, and human-like flexibility, are seen as the next generation of display technology. A team of Korean researchers has developed a stretchable display that can expand by 25% while maintaining clear image quality without distortion. It can also stretch and contract up to 5,000 times at 15% expansion without any performance degradation, making it the first deformation-free stretchable display with a negative Poisson's ratio* developed in Korea.
*Poisson’s ratio of -1: A ratio where both width and length stretch equally, expressed as a negative value. A positive Poisson's ratio represents the ratio where horizontal stretching leads to vertical contraction, which is the case for most materials.
KAIST (represented by President Kwang-Hyung Lee) announced on the 20th of August that a research team led by Professor Byeong-Soo Bae of the Department of Materials Science and Engineering (Director of the Wearable Platform Materials Technology Center) , in collaboration with the Korea Institute of Machinery & Materials (President Seoghyeon Ryu), successfully developed a stretchable display substrate that suppresses image distortion through omnidirectional stretchability.
Currently, most stretchable displays are made with highly elastic elastomer* materials, but these materials possess a positive Poisson's ratio, causing unavoidable image distortion when the display is stretched.
*Elastomer: A polymer with elasticity similar to rubber.
To address this, the introduction of auxetic* meta-structures has been gaining attention. Unlike conventional materials, auxetic structures have a unique 'negative Poisson's ratio,' expanding in all directions when stretched in just one direction. However, traditional auxetic structures contain many empty spaces, limiting their stability and usability in display substrates.
*Auxetic structure: A special geometric structure that exhibits a negative Poisson's ratio.
To tackle the issue of image distortion, Professor Bae's research team developed a method to create a seamless surface for the auxetic meta-structure, achieving the ideal negative Poisson's ratio of -1 and overcoming the biggest challenge in auxetic meta-structures.
To overcome the second issue of elastic modulus*, the team inserted a textile made of glass fiber bundles with a diameter of just 25 micrometers (a quarter of the thickness of human hair) into the elastomer material. They then filled the empty spaces with the same elastomer, creating a flat and stable integrated film without gaps.
*Elastic Modulus: The ratio that indicates the extent of deformation when force is applied to a material. A higher elastic modulus means that the material is less likely to deform under force.
The research team theoretically identified that the difference in elasticity between the auxetic structure and the elastomer material directly influences the negative Poisson's ratio and successfully achieved an elasticity difference of over 230,000 times, producing a film with a Poisson's ratio of -1, the theoretical limit.
< Figure 2. Deformation of S-AUX film. a) Configurations and visualized principal strain distribution of the optimized S-AUX film at various strain rates. b) Biaxial stretching image. While pristine elastomer shrinks in the directions that were not stretched, S-AUX film developed in this study expands in all directions simultaneously while maintaining its original shape. >
Professor Byeong-Soo Bae, who led the study, explained, "Preventing image distortion using auxetic structures in stretchable displays is a core technology, but it has faced challenges due to the many empty spaces in the surface, making it difficult to use as a substrate. This research outcome is expected to significantly accelerate commercialization through high-resolution, distortion-free stretchable display applications that utilize the entire surface."
This study, co-authored by Dr. Yung Lee from KAIST’s Department of Materials Science and Engineering and Dr. Bongkyun Jang from the Korea Institute of Machinery & Materials, was published on August 20th in the international journal Nature Communications under the title "A seamless auxetic substrate with a negative Poisson's ratio of –1".
The research was supported by the Wearable Platform Materials Technology Center at KAIST, the Korea Institute of Machinery & Materials, and LG Display.
< Figure 3. Structural configuration of the distortion-free display components on the S-AUX film and a contour image of a micro-LED chip transferred onto the S-AUX film. >
< Figure 4. Schematic illustrations and photographic images of the S-AUX film-based image: distortion-free display in its stretched state and released state. >
2024.09.20 View 2076 -
Extremely Stable Perovskite Nanoparticles Films for Next-Generation Displays
Researchers have reported an extremely stable cross-linked perovskite nanoparticle that maintains a high photoluminescence quantum yield (PLQY) for 1.5 years in air and harsh liquid environments. This stable material’s design strategies, which addressed one of the most critical problems limiting their practical application, provide a breakthrough for the commercialization of perovskite nanoparticles in next-generation displays and bio-related applications.
According to the research team led by Professor Byeong-Soo Bae, their development can survive in severe environments such as water, various polar solvents, and high temperature with high humidity without additional encapsulation. This development is expected to enable perovskite nanoparticles to be applied to high color purity display applications as a practical color converting material. This result was published as the inside front cover article in Advanced Materials.
Perovskites, which consist of organics, metals, and halogen elements, have emerged as key elements in various optoelectronic applications. The power conversion efficiency of photovoltaic cells based on perovskites light absorbers has been rapidly increased. Perovskites are also great promise as a light emitter in display applications because of their low material cost, facile wavelength tunability, high (PLQY), very narrow emission band width, and wider color gamut than inorganic semiconducting nanocrystals and organic emitters. Thanks to these advantages, perovskites have been identified as a key color-converting material for next-generation high color-purity displays. In particular, perovskites are the only luminescence material that meets Rec. 2020 which is a new color standard in display industry.
However, perovskites are very unstable against heat, moisture, and light, which makes them almost impossible to use in practical applications. To solve these problems, many researchers have attempted to physically prevent perovskites from coming into contact with water molecules by passivating the perovskite grain and nanoparticle surfaces with organic ligands or inorganic shell materials, or by fabricating perovskite-polymer nanocomposites. These methods require complex processes and have limited stability in ambient air and water. Furthermore, stable perovskite nanoparticles in the various chemical environments and high temperatures with high humidity have not been reported yet.
The research team in collaboration with Seoul National University develops siloxane-encapsulated perovskite nanoparticle composite films. Here, perovskite nanoparticles are chemically crosslinked with thermally stable siloxane molecules, thereby significantly improving the stability of the perovskite nanoparticles without the need for any additional protecting layer.
Siloxane-encapsulated perovskite nanoparticle composite films exhibited a high PLQY (> 70%) value, which can be maintained over 600 days in water, various chemicals (alcohol, strong acidic and basic solutions), and high temperatures with high humidity (85℃/85%). The research team investigated the mechanisms impacting the chemical crosslinking and water molecule-induced stabilization of perovskite nanoparticles through various photo-physical analysis and density-functional theory calculation.
The research team confirmed that displays based on their siloxane-perovskite nanoparticle composite films exhibited higher PLQY and a wider color gamut than those of Cd-based quantum dots and demonstrated perfect color converting properties on commercial mobile phone screens. Unlike what was commonly believed in the halide perovskite field, the composite films showed excellent bio-compatibility because the siloxane matrix prevents the toxicity of Pb in perovskite nanoparticle.
By using this technology, the instability of perovskite materials, which is the biggest challenge for practical applications, is greatly improved through simple encapsulation method.
“Perovskite nanoparticle is the only photoluminescent material that can meet the next generation display color standard. Nevertheless, there has been reluctant to commercialize it due to its moisture vulnerability. The newly developed siloxane encapsulation technology will trigger more research on perovskite nanoparticles as color conversion materials and will accelerate early commercialization,” Professor Bae said.
This work was supported by the Wearable Platform Materials Technology Center (WMC) of the Engineering Research Center (ERC) Project, and the Leadership Research Program funded by the National Research Foundation of Korea.
-Publication:
Junho Jang, Young-Hoon Kim, Sunjoon Park, Dongsuk Yoo, Hyunjin Cho, Jinhyeong Jang, Han Beom Jeong, Hyunhwan Lee, Jong Min Yuk, Chan Beum Park, Duk Young Jeon, Yong-Hyun Kim, Byeong-Soo Bae, and Tae-Woo Lee. “Extremely Stable Luminescent Crosslinked Perovskite Nanoparticles under Harsh Environments over 1.5 Years” Advanced Materials, 2020, 2005255. https://doi.org/10.1002/adma.202005255.
Link to download the full-text paper:
https://onlinelibrary.wiley.com/doi/10.1002/adma.202005255
-Profile: Prof. Byeong-Soo Bae (Corresponding author)
bsbae@kaist.ac.kr
Lab. of Optical Materials & Coating
Department of Materials Science and Engineering
Korea Advanced Institute of Science and Technology (KAIST)
2020.12.29 View 10981