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KAIST Captures Hot Holes: A Breakthrough in Light-to-Electricity Energy Conversion
When light interacts with metallic nanostructures, it instantaneously generates plasmonic hot carriers, which serve as key intermediates for converting optical energy into high-value energy sources such as electricity and chemical energy. Among these, hot holes play a crucial role in enhancing photoelectrochemical reactions. However, they thermally dissipate within picoseconds (trillionths of a second), making practical applications challenging. Now, a Korean research team has successfully developed a method for sustaining hot holes longer and amplifying their flow, accelerating the commercialization of next-generation, high-efficiency, light-to-energy conversion technologies. KAIST (represented by President Kwang Hyung Lee) announced on the 12th of March that a research team led by Distinguished Professor Jeong Young Park from the Department of Chemistry, in collaboration with Professor Moonsang Lee from the Department of Materials Science and Engineering at Inha University, has successfully amplified the flow of hot holes and mapped local current distribution in real time, thereby elucidating the mechanism of photocurrent enhancement. The team designed a nanodiode structure by placing a metallic nanomesh on a specialized semiconductor substrate (p-type gallium nitride) to facilitate hot hole extraction at the surface. As a result, in gallium nitride substrates aligned with the hot hole extraction direction, the flow of hot holes was amplified by approximately two times compared to substrates aligned in other directions. To fabricate the Au nanomesh, a polystyrene nano-bead monolayer assembly was first placed on a gallium nitride (p-GaN) substrate, and then the polystyrene nano-beads were etched to form a nanomesh template (Figure 1A). Then, a 20 nm thick gold nano-film was deposited, and the etched polystyrene nano-beads were removed to realize the gold nano-mesh structure on the GaN substrate (Figure 1B). The fabricated Au nanomesh exhibited strong light absorption in the visible range due to the plasmonic resonance effect (Figure 1C). > Furthermore, using a photoconductive atomic force microscopy (pc-AFM)-based photocurrent mapping system, the researchers analyzed the flow of hot holes in real time at the nanometer scale (one hundred-thousandth the thickness of a human hair). They observed that hot hole activation was strongest at "hot spots," where light was locally concentrated on the gold nanomesh. However, by modifying the growth direction of the gallium nitride substrate, hot hole activation extended beyond the hot spots to other areas as well. Through this research, the team discovered an efficient method for converting light into electrical and chemical energy. This breakthrough is expected to significantly advance next-generation solar cells, photocatalysts, and hydrogen production technologies. Professor Jeong Young Park stated, "For the first time, we have successfully controlled the flow of hot holes using a nanodiode technique. This innovation holds great potential for various optoelectronic devices and photocatalytic applications. For example, it could lead to groundbreaking advancements in solar energy conversion technologies, such as solar cells and hydrogen production. Additionally, the real-time analysis technology we developed can be applied to the development of ultra-miniaturized optoelectronic devices, including optical sensors and nanoscale semiconductor components." The study was led by Hyunhwa Lee (PhD., KAIST Department of Chemistry) and Yujin Park (Postdoc Researcher, University of Texas at Austin Department of Chemical Engineering) as co-first authors and Professors Moonsang Lee (Inha University, Department of Materials Science and Engineering) and Jeong Young Park (KAIST, Department of Chemistry) serving as corresponding authors. The research findings were published online in Science Advances on March 7. (Paper Title: “Reconfiguring hot-hole flux via polarity modulation of p-GaN in plasmonic Schottky architectures”, DOI: https://www.science.org/doi/10.1126/sciadv.adu0086) This research was supported by the National Research Foundation of Korea (NRF).
2025.03.17
View 997
KAIST Develops Neuromorphic Semiconductor Chip that Learns and Corrects Itself
< Photo. The research team of the School of Electrical Engineering posed by the newly deveoped processor. (From center to the right) Professor Young-Gyu Yoon, Integrated Master's and Doctoral Program Students Seungjae Han and Hakcheon Jeong and Professor Shinhyun Choi > - Professor Shinhyun Choi and Professor Young-Gyu Yoon’s Joint Research Team from the School of Electrical Engineering developed a computing chip that can learn, correct errors, and process AI tasks - Equipping a computing chip with high-reliability memristor devices with self-error correction functions for real-time learning and image processing Existing computer systems have separate data processing and storage devices, making them inefficient for processing complex data like AI. A KAIST research team has developed a memristor-based integrated system similar to the way our brain processes information. It is now ready for application in various devices including smart security cameras, allowing them to recognize suspicious activity immediately without having to rely on remote cloud servers, and medical devices with which it can help analyze health data in real time. KAIST (President Kwang Hyung Lee) announced on the 17th of January that the joint research team of Professor Shinhyun Choi and Professor Young-Gyu Yoon of the School of Electrical Engineering has developed a next-generation neuromorphic semiconductor-based ultra-small computing chip that can learn and correct errors on its own. < Figure 1. Scanning electron microscope (SEM) image of a computing chip equipped with a highly reliable selector-less 32×32 memristor crossbar array (left). Hardware system developed for real-time artificial intelligence implementation (right). > What is special about this computing chip is that it can learn and correct errors that occur due to non-ideal characteristics that were difficult to solve in existing neuromorphic devices. For example, when processing a video stream, the chip learns to automatically separate a moving object from the background, and it becomes better at this task over time. This self-learning ability has been proven by achieving accuracy comparable to ideal computer simulations in real-time image processing. The research team's main achievement is that it has completed a system that is both reliable and practical, beyond the development of brain-like components. The research team has developed the world's first memristor-based integrated system that can adapt to immediate environmental changes, and has presented an innovative solution that overcomes the limitations of existing technology. < Figure 2. Background and foreground separation results of an image containing non-ideal characteristics of memristor devices (left). Real-time image separation results through on-device learning using the memristor computing chip developed by our research team (right). > At the heart of this innovation is a next-generation semiconductor device called a memristor*. The variable resistance characteristics of this device can replace the role of synapses in neural networks, and by utilizing it, data storage and computation can be performed simultaneously, just like our brain cells. *Memristor: A compound word of memory and resistor, next-generation electrical device whose resistance value is determined by the amount and direction of charge that has flowed between the two terminals in the past. The research team designed a highly reliable memristor that can precisely control resistance changes and developed an efficient system that excludes complex compensation processes through self-learning. This study is significant in that it experimentally verified the commercialization possibility of a next-generation neuromorphic semiconductor-based integrated system that supports real-time learning and inference. This technology will revolutionize the way artificial intelligence is used in everyday devices, allowing AI tasks to be processed locally without relying on remote cloud servers, making them faster, more privacy-protected, and more energy-efficient. “This system is like a smart workspace where everything is within arm’s reach instead of having to go back and forth between desks and file cabinets,” explained KAIST researchers Hakcheon Jeong and Seungjae Han, who led the development of this technology. “This is similar to the way our brain processes information, where everything is processed efficiently at once at one spot.” The research was conducted with Hakcheon Jeong and Seungjae Han, the students of Integrated Master's and Doctoral Program at KAIST School of Electrical Engineering being the co-first authors, the results of which was published online in the international academic journal, Nature Electronics, on January 8, 2025. *Paper title: Self-supervised video processing with self-calibration on an analogue computing platform based on a selector-less memristor array ( https://doi.org/10.1038/s41928-024-01318-6 ) This research was supported by the Next-Generation Intelligent Semiconductor Technology Development Project, Excellent New Researcher Project and PIM AI Semiconductor Core Technology Development Project of the National Research Foundation of Korea, and the Electronics and Telecommunications Research Institute Research and Development Support Project of the Institute of Information & communications Technology Planning & Evaluation.
2025.01.17
View 3602
KAIST Alumni Association to Honor Alumni of the Year Award Winners
Photo 1. Photo of the KAIST Alumni of the Year Award Recipients (From left) UST President Lee-whan Kim, CEO Han Chung of iThree Systems Co., Ltd., CEO Dong Myung Kim of LG Energy Solution Co., Ltd., and Professor Hyun Myung of the School of Electrical Engineering at KAIST KAIST (President Kwang Hyung Lee) announced on Monday, the 13th of January that the Alumni Association (President Yun-Tae Lee) has selected its Alumni of the Year. This year’s honorees are: ▴ President Lee-whan Kim of the Korea National University of Science and Technology (UST), ▴ CEO Han Chung of i3 Systems, ▴ CEO Dong Myung Kim of LG Energy Solution, and ▴ Professor Hyun Myung of the School of Electrical Engineering at KAIST. The honorees were selected based on their achievements over the past year, and the award ceremony will be held at the 2025 KAIST Alumni Association New Year’s Gathering to be held at the L Tower in Seoul at 5 PM on Friday the 17th. The KAIST Alumni of the Year Award is an award presented by the Alumni Association to alumni who have contributed to the development of the country and the society or have brought honor to their alma mater through outstanding academic achievements and community service. Since its establishment in 1992, 126 recipients have been awarded. Lee-whan Kim (Master's graduate of Mechanical Engineering, 82), the President of the Korea National University of Science and Technology (UST), established a leading foundation for national science and technology policy and strategy, and played a leading role in innovating national science and technology capabilities through the advancement of the national research and development system and the advancement of science and technology personnel training. In particular, he played a pivotal role in the establishment of UST and the Korea Science Academy (KSA), and greatly contributed to establishing a foundation for the training and utilization of science and technology personnel. Han Chung (Master's graduate of Electrical Engineering, 91, with Ph.D. degree in 96), the CEO of i3 Systems, is a first-generation researcher in the field of domestic infrared detectors. He developed military detectors for over 30 years and founded i3 Systems, a specialized infrared detector company, in 1998. Currently, he supplies more than 80% of the infrared detectors used by the Korean military, and has also achieved export results to over 20 countries. Dong Myung Kim (Master's graduate of Materials Science and Engineering, 94, with Ph.D. degree in 98) the CEO of LG Energy Solution Co., Ltd. has led innovation in the battery field with his ceaseless exploration and challenging spirit, and is known as an authority in the secondary battery industry. He played a leading role in establishing K-Battery as a global leader, strengthened the country's future industrial competitiveness, and greatly contributed to the development of science and technology. Hyun Myung (Bachelor's graduate of Electrical Engineering, 92, with Master's degree in 94, and Ph.D. degree in 98) a Professor of Electrical Engineering, KAIST, won first place in the world at the Quadruped Robot Challenge (QRC) hosted by the IEEE’s International Conference on Robotics and Automation (ICRA) 2023 with the 'DreamWaQ' system, an AI walking technology based on deep reinforcement learning that utilizes non-video sensory technologies. He contributed to enhancing the competitiveness of the domestic robot industry by developing his own fully autonomous walking technology that recognizes the environment around the robot and finds the optimal path. Yun-Tae Lee, the 27th president of the KAIST Alumni Association, said, “KAIST alumni have been the driving force behind the growth of industries in all walks of life by continuously conducting research and development in the field of advanced science and technology for a long time,” and added, “I am very proud of the KAIST alumni award recipients who are leading science and technology on the world stage beyond Korea, and I sincerely thank them for their efforts and achievements.”
2025.01.15
View 2248
KAIST Wins CES 2025 Innovation Award, Showcasing Innovative Technologies
KAIST will showcase innovative technologies at the world’s largest technology fair, the Consumer Electronics Show (CES 2025). In addition, KAIST startups VIRNECT Inc., Standard Energy Inc., A2US Inc., and Panmnesia, Inc. won the 2025 CES Innovation Awards. < Image 1. 3D-Graphical Profile of CES 2025 KAIST Exhibition Booth > KAIST (President Kwang-Hyung Lee) announced on the 31st that it will operate a 140㎡ standalone booth at CES Eureka Park, which will be held in Las Vegas, USA from January 7th to 10th next year, to showcase KAIST's innovative technologies to global companies and investors. KAIST startups VIRNECT, Standard Energy, A2US, and Panmnesia, Inc. won the 2025 CES Innovation Awards. ▴VIRNECT won the Innovation Award in the ‘Industrial Equipment and Machinery’ category for ‘VisionX’, an AI-based smart glass for industrial sites; ▴Standard Energy Co., Ltd. won the Innovation Award in the ‘Smart City’ category for developing the world’s first vanadium-ion battery; ▴A2US won the Innovation Award in the ‘Environment & Energy’ category for its portable air purifier that eliminates bacteria, odors, and fine dust in the air with just water droplets; ▴Panmnesia, Inc. won the Innovation Award in the ‘Computer Peripherals and Accessories’ category for its ‘CXL-based GPU Memory Expansion Kit’ that can drastically reduce the cost of building AI infrastructure. < Image 2. (From left on the top row) VIRNECT, Standard Energy, (From left on the bottom row) A2US, Panmnesia, Inc. > This exhibition will feature 15 startups that are standing out in cutting-edge technologies such as artificial intelligence (AI), robotics, mobility, and sustainability. In particular, AI-based deep tech startups in various industries such as logistics, architecture, and medicine will take up half of the total, showcasing the companies’ innovative AI technologies. Polyphenol Factory Co.,Ltd introduces ‘Grabity’, a hair loss shampoo launched domestically, which applies the patented ingredient ‘LiftMax 308™’ that forms an instantaneous protective layer on the hair during the shampooing process. A real-time demonstration will be held at this exhibition hall so that visitors can experience the effects of the ingredient directly, and plans to enter the global market starting with the launch on Amazon in the US in January 2025. VIRNECT will present ‘VisionX’, a prototype that won the Innovation Award this time. The product provides a chatbot AI through an AI voice interface, and has a function that allows users to check the status of the equipment in real time through conversations with the AI and receive troubleshooting guidance through voice conversations, so users can experience it directly at the KAIST Hall. ‘Standard Energy’ plans to exhibit ‘Energy Tile’, an indoor ESS that utilizes the world’s first vanadium ion battery (hereinafter referred to as VIB). VIB is absolutely safe from fire and has high installation flexibility, so it can be applied to smart cities and AI data centers. ‘A2US’ is the only company in the world that has hydroxyl radical water production technology, and won the Innovation Award for its first product, an air purifier. In the future, it is expected to be widely commercialized in air and water purification, smart farms, food tech, and semiconductor cleaning using safe and environmentally friendly hydroxyl radical water. Panmnesia, Inc. won the CES Innovation Award for its GPU memory expansion solution equipped with its CXL 3.1 IP. By connecting a memory expansion device using Panmnesia’s CXL IP, the GPU’s memory capacity can be expanded to the terabyte level. Following the Innovation Award for ‘CXL-equipped AI Accelerator’ at CES 2024 last year, it is the only company to have won the Innovation Award for its AI-oriented CXL solution for two consecutive years. In addition, technologies from a total of 15 companies will be introduced, including ▴Omelet ▴NEXTWAVE ▴Planby Technologies ▴Cosmo Bee ▴ImpactAI ▴Roen Surgical ▴DIDEN Roboticss ▴Autopedia ▴OAQ ▴HydroXpand ▴BOOKEND ▴Sterri. On the central stage of the KAIST Hall, KAIST students selected as CES Student Supporters will conduct interviews with participating companies and promote the companies' innovative technologies and solutions. On the 8th, from 5 PM to 7 PM, a KAIST NIGHT event will be held where pre-invited investors and participating companies can network. Keon Jae Lee, the head of the Institute of Technology Value Creation, said, “Through CES 2025, we will showcase innovative technologies and solutions from startups based on KAIST’s deep science and deep tech, and lead commercialization in cutting-edge technology fields such as AI, robotics, mobility, and environment/energy. KAIST plans to further promote technology commercialization by supporting the growth and marketing of innovative startups through the Institute of Technology Value Creation and by strengthening global networks and expanding cooperation opportunities.”
2024.12.31
View 2723
KAIST Researchers Introduce New and Improved, Next-Generation Perovskite Solar Cell
- KAIST-Yonsei university researchers developed innovative dipole technology to maximize near-infrared photon harvesting efficiency - Overcoming the shortcoming of existing perovskite solar cells that cannot utilize approximately 52% of total solar energy - Development of next-generation solar cell technology with high efficiency and high stability that can absorb near-infrared light beyond the existing visible light range with a perovskite-dipole-organic semiconductor hybrid structure < Photo. (From left) Professor Jung-Yong Lee, Ph.D. candidate Min-Ho Lee, and Master’s candidate Min Seok Kim of the School of Electrical Engineering > Existing perovskite solar cells, which have the problem of not being able to utilize approximately 52% of total solar energy, have been developed by a Korean research team as an innovative technology that maximizes near-infrared light capture performance while greatly improving power conversion efficiency. This greatly increases the possibility of commercializing next-generation solar cells and is expected to contribute to important technological advancements in the global solar cell market. The research team of Professor Jung-Yong Lee of the School of Electrical Engineering at KAIST (President Kwang-Hyung Lee) and Professor Woojae Kim of the Department of Chemistry at Yonsei University announced on October 31st that they have developed a high-efficiency and high-stability organic-inorganic hybrid solar cell production technology that maximizes near-infrared light capture beyond the existing visible light range. The research team suggested and advanced a hybrid next-generation device structure with organic photo-semiconductors that complements perovskite materials limited to visible light absorption and expands the absorption range to near-infrared. In addition, they revealed the electronic structure problem that mainly occurs in the structure and announced a high-performance solar cell device that dramatically solved this problem by introducing a dipole layer*. *Dipole layer: A thin material layer that controls the energy level within the device to facilitate charge transport and forms an interface potential difference to improve device performance. Existing lead-based perovskite solar cells have a problem in that their absorption spectrum is limited to the visible light region with a wavelength of 850 nanometers (nm) or less, which prevents them from utilizing approximately 52% of the total solar energy. To solve this problem, the research team designed a hybrid device that combined an organic bulk heterojunction (BHJ) with perovskite and implemented a solar cell that can absorb up to the near-infrared region. In particular, by introducing a sub-nanometer dipole interface layer, they succeeded in alleviating the energy barrier between the perovskite and the organic bulk heterojunction (BHJ), suppressing charge accumulation, maximizing the contribution to the near-infrared, and improving the current density (JSC) to 4.9 mA/cm². The key achievement of this study is that the power conversion efficiency (PCE) of the hybrid device has been significantly increased from 20.4% to 24.0%. In particular, this study achieved a high internal quantum efficiency (IQE) compared to previous studies, reaching 78% in the near-infrared region. < Figure. The illustration of the mechanism of improving the electronic structure and charge transfer capability through Perovskite/organic hybrid device structure and dipole interfacial layers (DILs). The proposed dipole interfacial layer forms a strong interfacial dipole, effectively reducing the energy barrier between the perovskite and organic bulk heterojunction (BHJ), and suppressing hole accumulation. This technology improves near-infrared photon harvesting and charge transfer, and as a result, the power conversion efficiency of the solar cell increases to 24.0%. In addition, it achieves excellent stability by maintaining performance for 1,200 hours even in an extremely humid environment. > In addition, this device showed high stability, showing excellent results of maintaining more than 80% of the initial efficiency in the maximum output tracking for more than 800 hours even under extreme humidity conditions. Professor Jung-Yong Lee said, “Through this study, we have effectively solved the charge accumulation and energy band mismatch problems faced by existing perovskite/organic hybrid solar cells, and we will be able to significantly improve the power conversion efficiency while maximizing the near-infrared light capture performance, which will be a new breakthrough that can solve the mechanical-chemical stability problems of existing perovskites and overcome the optical limitations.” This study, in which KAIST School of Electrical Engineering Ph.D. candidate Min-Ho Lee and Master's candidate Min Seok Kim participated as co-first authors, was published in the September 30th online edition of the international academic journal Advanced Materials. (Paper title: Suppressing Hole Accumulation Through Sub-Nanometer Dipole Interfaces in Hybrid Perovskite/Organic Solar Cells for Boosting Near-Infrared Photon Harvesting). This study was conducted with the support of the National Research Foundation of Korea.
2024.10.31
View 4204
KAIST Changes the Paradigm of Drug Discovery with World's First Atomic Editing
In pioneering drug development, the new technology that enables the easy and rapid editing of key atoms responsible for drug efficacy has been regarded as a fundamental and "dream" technology, revolutionizing the process of discovering potential drug candidates. KAIST researchers have become the first in the world to successfully develop single-atom editing technology that maximizes drug efficacy. On October 8th, KAIST (represented by President Kwang-Hyung Lee) announced that Professor Yoonsu Park’s research team from the Department of Chemistry successfully developed technology that enables the easy editing and correction of oxygen atoms in furan compounds into nitrogen atoms, directly converting them into pyrrole frameworks, which are widely used in pharmaceuticals. < Image. Conceptual image illustrating the main idea of the research > This research was published in the prestigious scientific journal Science on October 3rd under the title "Photocatalytic Furan-to-Pyrrole Conversion." Many drugs have complex chemical structures, but their efficacy is often determined by a single critical atom. Atoms like oxygen and nitrogen play a central role in enhancing the pharmacological effects of these drugs, particularly against viruses. This phenomenon, where the introduction of specific atoms into a drug molecule dramatically affects its efficacy, is known as the "Single Atom Effect." In leading-edge drug development, discovering atoms that maximize drug efficacy is key. However, evaluating the Single Atom Effect has traditionally required multi-step, costly synthesis processes, as it has been difficult to selectively edit single atoms within stable ring structures containing oxygen or nitrogen. Professor Park’s team overcame this challenge by introducing a photocatalyst that uses light energy. They developed a photocatalyst that acts as a “molecular scissor,” freely cutting and attaching five-membered rings, enabling single-atom editing at room temperature and atmospheric pressure—a world first. The team discovered a new reaction mechanism in which the excited molecular scissor removes oxygen from furan via single-electron oxidation and then sequentially adds a nitrogen atom. Donghyeon Kim and Jaehyun You, the study's first authors and candidates in KAIST’s integrated master's and doctoral program in the Department of Chemistry, explained that this technique offers high versatility by utilizing light energy to replace harsh conditions. They further noted that the technology enables selective editing, even when applied to complex natural products or pharmaceuticals. Professor Yoonsu Park, who led the research, remarked, "This breakthrough, which allows for the selective editing of five-membered organic ring structures, will open new doors for building libraries of drug candidates, a key challenge in pharmaceuticals. I hope this foundational technology will be used to revolutionize the drug development process." The significance of this research was highlighted in the Perspective section of Science, a feature where a peer scientist of prominence outside of the project group provides commentary on an impactful research. This research was supported by the National Research Foundation of Korea’s Creative Research Program, the Cross-Generation Collaborative Lab Project at KAIST, and the POSCO Science Fellowship of the POSCO TJ Park Foundation.
2024.10.11
View 3385
KAIST begins full-scale cooperation with Taiwan’s Formosa Group
< (From left) Senior Vice President for Planning and Budget Kyung-Soo Kim, and Professor Minee Choi of the Department of Brain and Cognitive Sciences of KAIST along with Chairman of Formosa Group Sandy Wang and KAIST President Kwang-Hyung Lee, and Dean Daesoo Kim of KAIST College of Life Science and Bioengineering > KAIST is pursuing cooperation in the fields of advanced biotechnology and eco-friendly energy with Formosa Plastics Group, one of Taiwan's three largest companies. To this end, Chairman Sandy Wang, a member of Formosa Group's standing committee and leader of the group's bio and eco-friendly energy sector, will visit KAIST on the 13th of this month. This is the first time that the owner of Formosa Group has made an official visit to KAIST. Cooperation between the two institutions began last March when our university signed a memorandum of understanding on comprehensive exchange and cooperation with Ming Chi University of Science and Technology (明志科技大學), Chang Gung University(長庚大學), and Chang Gung Memorial Hospital(長庚記念醫院), three of many institutions established and supported by Formosa Group. Based on this, Chairman Sandy Wang, who visits our university to promote more exchanges and cooperation, talked about ‘the education of children and corporate social return and practice of his father, Chairman Yung-Ching Wang,’ through a special lecture for the school leadership as a part of the Monthly Lecture on KAIST’s Leadership Innovation Day. She then visited KAIST's research and engineering facilities related to Taiwan's future industries, such as advanced biotechnology and eco-friendly energy, and discussed global industry-academic cooperation plans. In the future, the two organizations plan to appoint adjunct professors and promote practical global cooperation, including joint student guidance and research cooperation. We plan to pursue effective mid- to long-term cooperation, such as conducting battery application research with the KAIST Next-Generation ESS Research Center and opening a graduate program specialized in stem cell and gene editing technology in connection with Chang Gung University and Chang Gung Memorial Hospital. The newly established cooperative relationship will also promote Formosa Group's investment and cooperation with KAIST's outstanding venture companies related to bio and eco-friendly energy to lay the foundation for innovative industrial cooperation between Taiwan and Korea. President Kwang-Hyung Lee said, “The Formosa Group has a global network, so we regard it to be a key partner that will position KAIST’s bio and engineering technology in the global stages.” He also said, “With Chairman Sandy Wang’s visit, Taiwan is emerging as a global economic powerhouse,” and added, “We expect to continue our close cooperative relationship with the company.” Formosa Group is a company founded by the late Chairman Yung-Ching Wang, the father of Chairman Sandy Wang. As the world's No. 1 plastic PVC producer, it is leading the core industries of Taiwan's economy, including semiconductors, steel, heavy industry, bio, and batteries. Chairman Yung-Ching Wang was respected by the Taiwanese people by setting an example of returning his wealth to society under the belief that the companies and assets he built ‘belonged to the people.’ Chang Gung University, Chang Gung Memorial Hospital, and Ming Chi University of Technology, which are pursuing cooperation with our university, were also established as part of the social contribution promoted by Chairman Yung-Ching Wang and are receiving financial support from Formosa Group.
2024.05.09
View 3749
KAIST Develops Sodium Battery Capable of Rapid Charging in Just a Few Seconds
Sodium (Na), which is over 500 times more abundant than lithium (Li), has recently garnered significant attention for its potential in sodium-ion battery technologies. However, existing sodium-ion batteries face fundamental limitations, including lower power output, constrained storage properties, and longer charging times, necessitating the development of next-generation energy storage materials. On the 11th of April, KAIST (represented by President Kwang Hyung Lee) announced that a research team led by Professor Jeung Ku Kang from the Department of Materials Science and Engineering had developed a high-energy, high-power hybrid sodium-ion battery capable of rapid charging. The innovative hybrid energy storage system integrates anode materials typically used in batteries with cathodes suitable for supercapacitors. This combination allows the device to achieve both high storage capacities and rapid charge-discharge rates, positioning it as a viable next-generation alternative to lithium-ion batteries. However, the development of a hybrid battery with high energy and high power density requires an improvement to the slow energy storage rate of battery-type anodes as well as the enhancement of the relatively low capacity of supercapacitor-type cathode materials. < Figure 1. Schematic synthetic procedures of high-capacity/high-rate anode and cathode materials for a sodium-ion hybrid energy storages (SIHES) and their proposed energy storage mechanisms. Synthetic procedures for (a) ultrafine iron sulfide-embedded S-doped carbon/graphene (FS/C/G) anode and (b) zeolitic imidazolate framework-derived porous carbon (ZDPC) cathode materials. (c) Proposed energy storage mechanisms of Na+ ions in FS/C/G anode and ClO-4 ions in ZDPC cathode for an SIHES. > To account for this, Professor Kang's team utilized two distinct metal-organic frameworks for the optimized synthesis of hybrid batteries. This approach led to the development of an anode material with improved kinetics through the inclusion of fine active materials in porous carbon derived from metal-organic frameworks. Additionally, a high-capacity cathode material was synthesized, and the combination of the cathode and anode materials allowed for the development of a sodium-ion storage system optimizing the balance and minimizing the disparities in energy storage rates between the electrodes. The assembled full cell, comprising the newly developed anode and cathode, forms a high-performance hybrid sodium-ion energy storage device. This device surpasses the energy density of commercial lithium-ion batteries and exhibits the characteristics of supercapacitors' power density. It is expected to be suitable for rapid charging applications ranging from electric vehicles to smart electronic devices and aerospace technologies. < Figure 2. Electrochemical characterizations of FS/C/G-20//ZDPC SIHES full cells (left). Ragone plots for FS/C/G-20//ZDPC (this work) and other previously reported sodium-ion electrochemical energy storage devices (right). > Professor Kang noted that the hybrid sodium-ion energy storage device, capable of rapid charging and achieving an energy density of 247 Wh/kg and a power density of 34,748 W/kg, represents a breakthrough in overcoming the current limitations of energy storage systems. He anticipates broader applications across various electronic devices, including electric vehicles. This research, co-authored by KAIST doctoral candidates Jong Hui Choi and Dong Won Kim, was published in the international journal Energy Storage Materials on March 29 with the title "Low-crystallinity conductive multivalence iron sulfide-embedded S-doped anode and high-surface-area O-doped cathode of 3D porous N-rich graphitic carbon frameworks for high-performance sodium-ion hybrid energy storages." The study was conducted with support from the Ministry of Science and ICT and the National Research Foundation of Korea through the Nanomaterial Technology Development Project.
2024.04.18
View 15392
KAIST and Hyundai Motors Collaborate to Develop Ultra-Fast Hydrogen Leak Detection within 0.6 Seconds
Recently, as the spread of eco-friendly hydrogen cars increases, the importance of hydrogen sensors is also on the rise. In particular, achieving technology to detect hydrogen leaks within one second remains a challenging task. Accordingly, the development of the world's first hydrogen sensor that meets the performance standards of the U.S. Department of Energy has become a hot topic. A team at KAIST led by Dr. Min-Seung Jo from Professor Jun-Bo Yoon's team in the Department of Electrical and Electronic Engineering has successfully achieved all of its desired performance indicators, meeting globally recognized standards through collaboration with the Electromagnetic Energy Materials Research Team at Hyundai Motor Company's Basic Materials Research Center and Professor Min-Ho Seo of Pusan National University. On January 10th, the research group announced that the world's first hydrogen sensor with a speed of less than 0.6 seconds had been developed. In order to secure faster and more stable hydrogen detection technology than existing commercialized hydrogen sensors, the KAIST team began developing a next-generation hydrogen sensor in 2021 together with Hyundai Motor Company, and succeeded after two years of development. < Figure 1. (Left) The conceptual drawing of the structure of the coplanar heater-integrated hydrogen sensor. Pd nanowire is stably suspended in the air even with its thickness of 20 nm. (Right) A graph of hydrogen sensor performance operating within 0.6 seconds for hydrogen at a concentration of 0.1 to 4% > Existing hydrogen sensor research has mainly focused on sensing materials, such as catalytic treatments or the alloying of palladium (Pd) materials, which are widely used in hydrogen sensors. Although these studies showed excellent performance with certain performance indicators, they did not meet all of the desired performance indicators and commercialization was limited due to the difficulty of batch processing. To overcome this, the research team developed a sensor that satisfied all of the performance indicators by combining independent micro/nano structure design and process technology based on pure palladium materials. In addition, considering future mass production, pure metal materials with fewer material restrictions were used rather than synthetic materials, and a next-generation hydrogen sensor was developed that can be mass-produced based on a semiconductor batch process. The developed device is a differential coplanar device in which the heater and sensing materials are integrated side by side on the same plane to overcome the uneven temperature distribution of existing gas sensors, which have a structure where the heater, insulating layer, and sensing materials are stacked vertically. The palladium nanomaterial, which is a sensing material, has a completely floating structure and is exposed to air from beneath, maximizing the reaction area with a gas to ensure a fast reaction speed. In addition, the palladium sensing material operates at a uniform temperature throughout the entire area, and the research team was able to secure a fast operation speed, wide sensing concentration, and temperature/humidity insensitivity by accurately controlling temperature-sensitive sensing performance. < Figure 2. Electron microscopy of the coplanar heater-integrated hydrogen sensor (left) Photo of the entire device (top right) Pd nanowire suspended in the air (bottom right) Cross section of Pd nanowire > The research team packaged the fabricated device with a Bluetooth module to create an integrated module that wirelessly detects hydrogen leaks within one second and then verified its performance. Unlike existing high-performance optical hydrogen sensors, this one is highly portable and can be used in a variety of applications where hydrogen energy is used. Dr. Min-Seung Jo, who led the research, said, “The results of this research are of significant value as they not only operate at high speeds by exceeding the performance limits of existing hydrogen sensors, but also secure the reliability and stability necessary for actual use, and can be used in various places such as automobiles, hydrogen charging stations, and homes.” He also revealed his future plans, saying, “Through the commercialization of this hydrogen sensor technology, I would like to contribute to advancing the safe and eco-friendly use of hydrogen energy.” < Figure 3. (Left) Real-time hydrogen detection results from the coplanar heater-integrated hydrogen sensor integrated and packaged in wireless communication and an app for mobile phone. (Middle) LED blinking cycle control in accordance with the hydrogen concentration level. (Right) Results of performance confirmation of the detection within 1 second in a real-time hydrogen leak demo > The research team is currently working with Hyundai Motor Company to manufacture the device on a wafer scale and then mount it on a vehicle module to further verify detection and durability performance. This research, conducted by Dr. Min-Seung Jo as the first author, has three patent applications filed in the U.S. and Korea, and was published in the renowned international academic journal 'ACS Nano'. (Paper title: Ultrafast (∼0.6 s), Robust, and Highly Linear Hydrogen Detection up to 10% Using Fully Suspended Pure Pd Nanowire). (Impact Factor: 18.087). ( https://pubs.acs.org/doi/10.1021/acsnano.3c06806?fig=fig1&ref=pdf ) The research was conducted through support from the National Research Foundation of Korea's Nano and Materials Technology Development Project and support and joint development efforts from Hyundai Motor Company's Basic Materials Research Center.
2024.01.25
View 4781
A KAIST Research Team Develops a Smart Color-Changing Flexible Battery with Ultra-high Efficiency
With the rapid growth of the smart and wearable electronic devices market, smart next-generation energy storage systems that have energy storage functions as well as additional color-changing properties are receiving a great deal of attention. However, existing electrochromic devices have low electrical conductivity, leading to low efficiency in electron and ion mobility, and low storage capacities. Such batteries have therefore been limited to use in flexible and wearable devices. On August 21, a joint research team led by Professor Il-Doo Kim from the KAIST Department of Materials Science and Engineering (DMSE) and Professor Tae Gwang Yun from the Myongji University Department of Materials Science and Engineering announced the development of a smart electrochromic Zn-ion battery that can visually represent its charging and discharging processes using an electrochromic polymer anode incorporated with a “π-bridge spacer”, which increases electron and ion mobility efficiency. Batteries topped with electrochromic properties are groundbreaking inventions that can visually represent their charged and discharged states using colors, and can be used as display devices that cut down energy consumption for indoor cooling by controlling solar absorbance. The research team successfully built a flexible and electrochromic smart Zn-ion battery that can maintain its excellent electrochromic and electrochemical properties, even under long-term exposure to the atmosphere and mechanical deformations. < Figure 1. Electrochromic zinc ion battery whose anode is made of a polymer that turns dark blue when charged and transparent when discharged. > To maximize the efficiency of electron and ion mobility, the team modelled and synthesized the first π-bridge spacer-incorporated polymer anode in the world. π-bonds can improve the mobility of electrons within a structure to speed up ion movement and maximize ion adsorption efficiency, which improves its energy storage capacity. In anode-based batteries with a π-bridge spacer, the spacer provides room for quicker ion movement. This allows fast charging, an improved zinc-ion discharging capacity of 110 mAh/g, which is 40% greater than previously reported, and a 30% increase in electrochromic function that switches from dark blue to transparent when the device is charged/discharged. In addition, should the transparent flexible battery technology be applied to smart windows, they would display darker colors during the day while they absorb solar energy, and function as a futuristic energy storage technique that can block out UV radiation and replace curtains. < Figure 2. A schematic diagram of the structure of the electrochromic polymer with π-π spacer and the operation of a smart flexible battery using this cathode material. > < Figure 3. (A) Density Functional Theory (DFT) theory-based atomic and electronic structure analysis. (B) Comparison of rate characteristics for polymers with and without π-bridge spacers. (C) Electrochemical performance comparison graph with previously reported zinc ion batteries. The anode material, which has an electron donor-acceptor structure with a built-in π-bridge spacer, shows better electrochemical performance and electrochromic properties than existing zinc ion batteries and electrochromic devices. > Professor Il-Doo Kim said, “We have developed a polymer incorporated with a π-bridge spacer and successfully built a smart Zn-ion battery with excellent electrochromic efficiency and high energy storage capacity.” He added, “This technique goes beyond the existing concept of batteries that are used simply as energy storage devices, and we expect this technology to be used as a futuristic energy storage system that accelerates innovation in smart batteries and wearable technologies.” This research, co-first authored by the alums of KAIST Departments of Material Sciences of Engineering, Professor Tae Gwang Yun of Myongji University, Dr. Jiyoung Lee, a post-doctoral associate at Northwestern University, and Professor Han Seul Kim at Chungbuk National University, was published as an inside cover article for Advanced Materials on August 3 under the title, “A π-Bridge Spacer Embedded Electron Donor-Acceptor Polymer for Flexible Electrochromic Zn-Ion Batteries”. < Figure 4. Advanced Materials Inside Cover (August Issue) > This research was supported by the Nanomaterial Technology Development Project under the Korean Ministry of Science and ICT, the Nano and Material Technology Development Project under the National Research Foundation of Korea, the Successive Academic Generation Development Project under the Korean Ministry of Education, and the Alchemist Project under the Korean Ministry of Trade, Industry & Energy.
2023.09.01
View 6717
A KAIST Research Team Develops an Ultra-High Performing “Universal Electrode” for Next-Generation Fuel Cells
Fuel cells are devices that generate electricity with high efficiency using hydrogen, a clean energy source, and are expected to play an important part in the upcoming hydrogen society. The recent development of an excellent universal electrode material that is applicable to all next-generation fuel cells and can withstand 700 hours of operation has therefore garnered a great deal of attention. On August 9, a joint research team led by Prof. WooChul Jung from the KAIST Department of Materials Science and Engineering, Prof. Kang Taek Lee from the KAIST Department of Mechanical Engineering, and Prof. Jun Hyuk Kim from the Department of Chemical Engineering at Hongik University announced the development of an electrode material that is applicable to both oxygen- and proton-conducting solid oxide cells. Depending on the type of ion conducted by the electrolyte, ceramic fuel cells are categorized into either solid oxide fuel cells (SOFC) or protonic ceramic fuel cells (PCFC). As they can both convert between electricity and hydrogen production, fuel cells can be categorized into a total of four device types. These devices are applicable in hydrogen fuel cell vehicles, hydrogen charging stations, and power generation systems, and are henceforth emerging as core next-generation technologies for a carbon-neutral society. However, these devices have a chronic problem where the speed of their slowest reaction would decrease with a drop of driving temperature, which greatly reduces device efficiency. Various studies have been conducted to solve this, but most reported that electrode materials have low catalytic activity and their applications are limited to specific devices, which limits them from being used as SOFCs that require reversible power conversion and hydrogen production. < Figure 1. Schematic diagram of high-performance oxygen ion conductive solid oxide fuel cell (SOFC) and proton conductive ceramic fuel cell (PCFC) operates with the new universal electrodes > To solve this issue, the research team doped a perovskite oxide material with Ta5+, a high valence ion that did not receive much attention in the field. Through this, the team successfully stabilized what is usually a highly unstable crystal structure, and confirmed that catalytic activity improved by 100 times. The electrode material developed by the team was applied to all four of the mentioned device types. Furthermore, their efficiencies were greater than any of the devices reported thus far, and showed excellent performance by stably running for much longer (700 hours) compared to existing materials that deteriorated within the first 100 hours of operation. < Figure 2. (a) Power conversion and hydrogen production performance chart for the protonic ceramic fuel cell (PCFC) with the new universal electrodes (b) and performance comparison with other reported devices > This research, in which KAIST’s Ph.D. candidates Dongyeon Kim and Sejong Ahn, and Professor Jun Hyuk Kim from Hongik University contributed as co-first authors, was published in the internationally renowned Energy & Environmental Science under the title, "Oxygen-Electrode for Reversible Solid Oxide Electrochemical Cells at Reduced Temperatures". Prof. WooChul Jung said, “We broke free from the idea that we must develop a completely new material to solve an existing problem, and instead suggested a way to control the crystal structure of a lesser-known material to develop a high-efficiency fuel cell, and that’s what makes these results more significant.” Prof. Kang Taek Lee added, “Unlike previously reported materials that could only be applied to one device type at a time, our material has the flexibility of being applicable to all four. We therefore look forward to its contribution in the commercialization of eco-friendly energy technology including fuel cells and water-splitting equipment for hydrogen production.” This research was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean Ministry of Science and ICT.
2023.08.22
View 6360
KAIST develops biocompatible adhesive applicable to hair transplants
Aside from being used as a new medical adhesive, the new material can be applied to developing a new method of hair transplants, which cannot be repeated multiple times using current method of implanting the wholly intact follicles into the skin. Medical adhesives are materials that can be applied to various uses such as wound healing, hemostasis, vascular anastomosis, and tissue engineering, and is expected to contribute greatly to the development of minimally invasive surgery and organ transplants. However, adhesives with high adhesion, low toxicity, and capable of decomposing in the body are rare. Adhesives based on natural proteins, such as fibrin and collagen, have high biocompatibility but insufficient adhesive strength. Synthetic polymer adhesives based on urethane or acrylic have greater adhesion but do not decompose well and may cause an inflammatory reaction in the body. A joint research team led by Professor Myungeun Seo and Professor Haeshin Lee from the KAIST Department of Chemistry developed a bio-friendly adhesive from biocompatible polymers using tannic acid, the source of astringency in wine. The research team focused on tannic acid, a natural polyphenolic product. Tannic acid is a polyphenol present in large amounts in fruit peels, nuts, and cacao. It has a high affinity and coating ability on other substances, and we sense the astringent taste in wine when tannic acid sticks to the surface of our tongue. When tannic acid is mixed with hydrophilic polymers, they form coacervates, or small droplets of jelly-like fluids that sink. If the polymers used are biocompatible, the mixture can be applied as a medical adhesive with low toxicity. However, coacervates are fundamentally fluid-like and cannot withstand large forces, which limits their adhesive capabilities. Thus, while research to utilize it as an adhesive has been actively discussed, a biodegradable material exhibiting strong adhesion due to its high shear strength has not yet been developed. The research team figured out a way to enhance adhesion by mixing two biocompatible FDA-approved polymers, polyethylene glycol (PEG) and polylactic acid (PLA). While PEG, which is used widely in eyedrops and cream, is hydrophilic, PLA, a well-known bioplastic derived from lactic acid, is insoluble in water. The team combined the two into a block copolymer, which forms hydrophilic PLA aggregates in water with PEG blocks surrounding them. A coacervate created by mixing the micelles and tannic acid would behave like a solid due to the hard PLA components, and show an elastic modulus improved by a thousand times compared to PEG, enabling it to withstand much greater force as an adhesive. Figure 1. (Above) Principle of biodegradable adhesive made by mixing poly(ethylene glycol)-poly(lactic acid) diblock copolymer and tannic acid in water. Yellow coacervate is precipitated through hydrogen bonding between the block copolymer micelles and tannic acid, and exhibits adhesion. After heat treatment, hydrogen bonds are rearranged to further improve adhesion. (Bottom) Adhesion comparison. Compared to using poly(ethylene glycol) polymer (d), it can support 10 times more weight when using block copolymer (e) and 60 times more weight after heat treatment (f). The indicated G' values represent the elastic modulus of the material. Furthermore, the research team observed that the material’s mechanical properties can be improved by over a hundred times through a heating and cooling process that is used to heat-treat metals. They also discovered that this is due to the enforced interactions between micelle and tannic acid arrays. The research team used the fact that the material shows minimal irritation to the skin and decomposes well in the body to demonstrate its possible application as an adhesive for hair transplantation through an animal experiment. Professor Haeshin Lee, who has pioneered various application fields including medical adhesives, hemostatic agents, and browning shampoo, focused on the adhesive capacities and low toxicity of polyphenols like tannic acid, and now looks forward to it improving the limitations of current hair transplant methods, which still involve follicle transfer and are difficult to be repeated multiple times. Figure 2. (a) Overview of a hair transplantation method using a biodegradable adhesive (right) compared to a conventional hair transplantation method (left) that transplants hair containing hair follicles. After applying an adhesive to the tip of the hair, it is fixed to the skin by implanting it through a subcutaneous injection, and repeated treatment is possible. (b) Initial animal test results. One day after 15 hair transplantation, 12 strands of hair remain. If you pull the 3 strands of hair, you can see that the whole body is pulled up, indicating that it is firmly implanted into the skin. All strands of hair applied without the new adhesive material fell off, and in the case of adhesive without heat treatment, the efficiency was 1/7. This research was conducted by first co-authors Dr. Jongmin Park (currently a senior researcher at the Korea Research Institute of Chemical Technology) from Professor Myeongeun Seo’s team and Dr. Eunsook Park from Professor Haeshin Lee’s team in the KAIST Department of Chemistry, and through joint research with the teams led by Professor Hyungjun Kim from the KAIST Department of Chemistry and Professor Siyoung Choi from the Department of Chemical and Biomolecular Engineering. The research was published online on August 22 in the international journal Au (JACS Au) under the title Biodegradable Block Copolymer-Tannic Acid Glue. This study was funded by the Support Research Under Protection Project of the National Research Foundation (NRF), Leading Research Center Support Project (Research Center for Multiscale Chiral Structure), Biodegradable Plastics Commercialization and Demonstration Project by the Ministry of Trade and Industry, and institutional funding from the Korea Research Institute of Chemical Technology.
2022.10.07
View 9834
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