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Review of organophosphonate nerve agent remediation and sensing chemistry
Professor David Churchill, Dept. of Chemistry, KAIST
Scientists in Daejeon, South Korea and Lexington, Kentucky (USA) have recently published a review on the subject of nerve agent remediation and probing chemistry (Chemical Reviews, DOI:10.1021/cr100193y). This article endeavored to pursue organophosphonate nerve agent chemistry deeply and comprehensively and to reflect that decontamination / sensing and nerve agents / pesticides are quite inextricable: when one tries to degrade nerve agents one also needs to detect what components are still present “downstream,” etc. Nerve agents and many pesticides also share a common generalized organophosphate / -phosphonate structure.
Also, the use of simulant molecules (mimics) and a consideration of the closely related organophosphonate pesticides were also treated comprehensively in the Review. The authors reached back into the literature when developing some sections to make important connections to the contemporary topics of interest. The review also includes industrial insights.
Kibong Kim, Olga G. Tsay and David G. Churchill of the Department of Chemistry at KAIST and David A. Atwood of the Department of Chemistry of the University of Kentucky endeavored to "make a variety of connections in research strategies and (sub-) fields to present what is still possible, fruitful, practical, and necessary and to facilitate a current comprehensive molecular level understanding of organophosphonate degradation and sensing," Churchill says.
The authors feel that for the time being, researchers in varying research areas “can use this manuscript effectively when considering future research directions.”
2011.09.19 View 9976 -
KAIST Online Electirc Vehicle Introduced by CNN
CNN aired KAIST’s Online Electric Vehicle (OLEV) on August 29, 2011 in its program called “Eco Solutions” that reports on meeting people with innovative solutions to preserve the planet. The reporter went to Seoul Grand Park, an amusement park and introduced an online electric tram developed by KAIST and operated on a daily basis for park visitors since July 29, 2011. KAIST has designed different types of OLEVs including bus, SUV, and tram. The reporter said that “the online electric tram” at the park provides visitors with a “cleaner, greener, and convenience since it charges as you go.” Currently, three OLEVs are running inside the park, and KAIST plans to replace the rest of existing diesel trams with OLEVs in the near future.
CNN Link: http://edition.cnn.com/CNNI/Programs/eco.solutions/index.html
Youtube Link: http://www.youtube.com/watch?v=QLzmFFqPJfo
2011.09.09 View 12121 -
Op-Ed by MIT President, Manufacturing a Recovery, New York Times, August 29, 2011
New York Times carried an opinion piece of MIT President, Susan Hockfield. Dr. Hockfield put emphasis on the importance of recovering manufacturing to revive the US economy and suggested investments in the development of high technology and “tight integration of design production” through “networks of innovation, lab research to new production processes, and business models.” For the op-ed piece, please go to
http://www.nytimes.com/2011/08/30/opinion/manufacturing-a-recovery.html?_r=2.
2011.08.31 View 11536 -
Scientists develop highly efficient industrial catalyst
http://english.yonhapnews.co.kr/business/2011/07/14/48/0501000000AEN20110714009600320F.HTML
SEOUL, July 15 (Yonhap) -- South Korean scientists said Friday that they have developed a highly efficient nanoporous industrial catalyst that can have a considerable impact on chemical and oil-refining sectors.
The team of scientists led by Ryoo Ryong, a chemistry professor at the Korea Advanced Institute of Science and Technology (KAIST), said the solid zeolite compound developed in the laboratory has a reaction speed five to 10 times faster than that of conventional materials.
Zeolite, which is made from silica and aluminium, is frequently used as an absorbent, water purifier and in nuclear reprocessing, although it is mainly employed in the chemical industry.
The annual size of the zeolite market is estimated at US$2.5 billion with output using the material topping $30 billion. At present, 41 percent of all catalysts used in the chemical sector are nano-scale zeolite materials.
The KAIST team said that because the new zeolite is made up of different sized pores, the material can be used as a catalyst when existing materials are unable to act as a changing agent.
"Existing zeolites only have pores under 1 nanometer in diameter, but the new material has holes that range from 1 nanometer to 3.5 nanometers, which are all arranged in a regular honeycomb arrangement," Ryoo said. A nanometer is one-billionth of a meter.
He said the ability to have both micro- and meso-sized pores is key to the faster reaction speed that is an integral part of raising efficiency. The South Korean researchers used a so-called surfactant process to make the different sizes of pores.
The development is a breakthrough because researchers and companies such as Exxon Mobil Corp. have been trying to build zeolite with different sizes of pores for the past two decades without making serious headway. There are more than 200 different types of zeolites in the world.
Ryoo, who received funding from the government, has requested intellectual property rights for the discovery, which has been published in the latest issue of Science magazine. He also developed another zeolite in the past that can transform methanol to gasoline up to 10 times more efficiently than existing catalysts.
Exxon Mobil has expressed interest in the two zeolites made by Ryoo"s team. Undisclosed South Korean petrochemical companies have also made inquiries that may lead to commercial development in the future.
"There are some technical issues to resolve, mainly related with mass production and stability," the scientist said.
He said full-fledge production will be determined by how much companies are willing to spend on research to speed up development that can bring down overall production costs.
The KAIST team said it took two years to make the new zeolite, which can be custom made to meet specific needs.
(END)
2011.07.15 View 13878
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KAIST Successfully Demonstrates Mobile Harbor in the Open Sea
Busan, South Korea—Large container ships are no longer required to come into ports to transport cargo, as KAIST has developed an innovative technology that will transform the paradigm of today’s cargo handling operations. A Mobile Harbor is a vessel that carries a large stabilized crane with a smart spreader and multistage trolley system, enabling the loading and unloading of ship cargo on the wavy open sea. Following a successful docking of two vessels at sea in April of this year, KAIST conducted a full scope of Mobile Harbor operations in the inner sea of Busan, South Korea, on June 29, 2011.
Initiated in 2009, the Mobile Harbor (MH) is one of the university’s flagship research projects, which aims to provide a new growth engine that will lead the Korean economy to the next level of advancement, and to develop green technology through multidisciplinary and convergence research. The idea of MH came to light when thinking outside the box (why can’t a harbor go out to meet a ship on voyage and retrieve goods instead of ships coming into the harbor?) to improve problems relating to the current maritime transport system, such as port congestion, environmental issues caused by heavy sea transport, increased demand for supersized container ships, and the need for port construction and expansion.
The essential technology to establish a Mobile Harbor is a docking system and crane system that can overcome the obstacles imposed by the sea, i.e., waves and wind. Connecting two operating vessels of different sizes in the unpredictable and ever-changing environment of the sea was regarded as “impossible” and had never been tried before, but, on April 26, 2011, KAIST successfully demonstrated the technology to moor vessels safely and securely.
The Mobile Harbor has a unique way of mooring vessels that are anchored at sea: its flexibly designed robot arms with a square-shape vacuum suction pad at the tip reach out and attach to the hull of a container ship for docking. Each robot arm is connected to a cable and winch that further add stability to the Mobile Harbor. Foam-filled fenders are placed between the Mobile Harbor and the container ship, thereby maintaining a safe distance to prevent collisions.
The crane system consists of a multistage trolley, smart spreader, and tension controller, all of which provide the crane with functionality and stability to move around cargo containers in the sea. The crane system also has various sensors like cameras and laser scanners, and therefore, it can gauge the movement of the spreader and ships as well as trace a target container in real time. As a result, the spreader, a container grabbing device, is free from the swing motions when lifting and putting down cargo and grabs a target container safely in the wavy open sea.
During today’s at-sea demonstration in Busan, a research team from the KAIST Mobile Harbor Center docked a Mobile Harbor (a barge ship) right next to a container vessel (the other barge ship) and repeated freight transport operations between the two ships, presenting the great potential to commercialize the Mobile Harbor technology.
The project has been implemented in collaboration with industries, research institutes, and universities in such fields as mechanical engineering, robotics, automation engineering, and ocean systems engineering. The demonstration proceeded with a wide range of participants including researchers, engineers, government officials, and entrepreneurs from Korea and around the world.
Byung-Man Kwak, Director of the KAIST Mobile Harbor Center, explained his feelings on the successful demonstration:
“It’s been a remarkable journey to develop a Mobile Harbor from scratch, and I’m genuinely thrilled to showcase what we have accomplished so far. Today’s demonstration of Mobile Harbor’s core technologies will really change the face of our maritime transportation system. We will be able to deliver more goods to global markets and consumers via sea route, not necessarily building more ports or expanding the existing harbors. KAIST’s Mobile Harbor will also significantly cut down the high cost related to overland transportation of cargo and in return, contribute to the reduction of carbon emission.”
The Center has received much interest in possible market migration and broader application of the Mobile Harbor from businesses and organizations, e.g., US Office of Naval Research, King Fahd University of Petroleum and Minerals, Saudi Aramco, POSCO, and the Korean Navy.
2011.07.06 View 18510 -
KAIST Tops Patent List Among Domestic Universities, Chosun Ilbo, July 5, 2011
According to the Korean Intellectual Property Office, KAIST took the first place among the universities in Korea registering patents from 2006 to 2010. For the article from Chosun Ilbo, please go to the below link:
http://english.chosun.com/site/data/html_dir/2011/07/05/2011070500743.html
2011.07.05 View 11567
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Yonhap News, Scientists Develop Nitrogen-Doped Graphene Supercapacitor, June 6, 2011
Yonhap News Agency, South Korea’s wire news agency, reported that KAIST’s research team developed “a new type of power storage technology using nitrogen and graphene.”
http://www.bernama.com/bernama/v5/newsworld.php?id=591725
2011.06.08 View 10686
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The Atlantic, 10 Essential Books for Thought-Provoking Summer Reading, May 31, 2011
The Atlantic, a reputable monthly magazine published in the US, has released a list of summer reading that includes a cross-disciplinary selection of the 10 most interesting, though-provoking books to read. For the list and a brief introduction about each book, please visit the website below:
http://www.theatlantic.com/life/print/2011/05/10-essential-books-for-thought-provoking-summer-reading/239657/
2011.06.01 View 9031
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Professor Choi Han Lim receives Automatica Applications Paper Price
Professor Choi Han Lim of the Department of Aerospace received ‘Automatica Applications Paper Prize’ for the first time ever for a Korean.
Professor Choi published a paper in the Automatica magazine with the topic of ‘Continuous Trajectory Planning of Mobile Sensors for Informative Forecasting’.
Professor Choi dealt with most efficient measuring methods for mobile sensor platforms thereby improving the performance of anticipating environmental changes and proposed key theories for problem solving and also an efficient algorithm.
The research was conducted in cooperation with MIT Department of Aerospace Professor Jonathan How with the support of the National Science Foundation.
Automatica
Journal published by the International Federation of Automatic Control and has been awarding the Automatica Paper Prize every three years.
2011.05.31 View 9850
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Displaybank, KAIST Develops Flexible Display Metal Wiring Technology, May 27, 2011
On May 26, Korea Advanced Institute of Science (KAIST) announced that team of Prof. Yang from the Department of Mechanical Engineering developed flexible display metal wiring manufacturing-technology. For the article, please follow the link,
http://www.displaybank.com/eng/info/sread.php?id=5877
2011.05.31 View 10212
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President Seo Nam Pyo receives DTU Gold Medal
President Seo Nam Pyo receives DTU Gold Medal on the 6th of May in the DTU Annual Commemoration Day Ceremony.
The DTU has recognized the achievements, innovative ideas, and great effort made by President Seo in heightening the world level of engineering education and his success in improving the status of science and technology of Korea.
The Technical University of Denmark was established in 1829 and is known as the best engineering university in Scandinavia and awards a gold medal annually to a person that is recognized for their accomplishment in the field of science and technology.
2011.05.31 View 9272
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Professor Hwang Kyu Young Receives Outstanding Contributions Award from DASFAA
Professor Hwang Kyu Young received the 2011 Outstanding Contributions Award from the International Conference on Database Systems for Advanced Applications (DASFAA).
Professor Hwang was the Chairman, Vice Chairman, Executive, etc. of the DASFAA Steering Committee for the past 12 years and has been leading the development in the field of database in the Asia/Pacific Region. He was also the editor in chief of The VLDB Journal which is the leading magazine in the field of database and the member of ACM SIGMOD Jim Gray Dissertation Award Committee, VLDB 10-year Best Paper Award Committee, and IEEE ICDE Influential Paper Awards Committee. He receives the Outstanding Contributions Award for ensuring high standards in world database research.
2011.05.31 View 11011