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KAIST, Production Temperature ↓ by 500°C, Power Output ↑ 2x… Next-Generation Ceramic Electrochemical Cell Reborn
<(Top row, from left) Professor Kang Taek Lee, Ph.D candidate Yejin Kang, Dr. Dongyeon Kim, (Bottom row, from left) M.S candidate Mincheol Lee, Ph.D candidate Seeun Oh, Ph.D candidate Seungsoo Jang, Ph.D candidate Hyeonggeun Kim>
As power demand surges in the AI era, the “protonic ceramic electrochemical cell (PCEC),” which can simultaneously produce electricity and hydrogen, is gaining attention as a next-generation energy technology. However, this cell has faced the technical limitation of requiring an ultra-high production temperature of 1,500°C. A KAIST research team has succeeded in establishing a new manufacturing process that lowers this limit by more than 500°C for the first time in the world.
KAIST (President Kwang Hyung Lee) announced on the 4th of December that Professor Kang Taek Lee’s research team in the Department of Mechanical Engineering developed a new process that enables the fabrication of high-performance protonic ceramic electrochemical cells at temperatures more than 500°C lower than before, using “microwave + vapor control technology” that leverages microwave heating principles and the diffusion environment of chemical vapor generated from specific chemical components.
The electrolyte—the key material of protonic ceramic electrochemical cells—contains barium (Ba), and barium easily evaporates at temperatures above 1,500°C, which has been the main cause of performance degradation. Therefore, the ability to harden the ceramic electrolyte at a lower temperature has been the core issue that determines cell performance.
As power demand surges in the AI era, the “protonic ceramic electrochemical cell (PCEC),” which can simultaneously produce electricity and hydrogen, is gaining attention as a next-generation energy technology. However, this cell has faced the technical limitation of requiring an ultra-high production temperature of 1,500°C. A KAIST research team has succeeded in establishing a new manufacturing process that lowers this limit by more than 500°C for the first time in the world.
KAIST (President Kwang Hyung Lee) announced on the 4th of December that Professor Kang Taek Lee’s research team in the Department of Mechanical Engineering developed a new process that enables the fabrication of high-performance protonic ceramic electrochemical cells at temperatures more than 500°C lower than before, using “microwave + vapor control technology” that leverages microwave heating principles and the diffusion environment of chemical vapor generated from specific chemical components.
The electrolyte—the key material of protonic ceramic electrochemical cells—contains barium (Ba), and barium easily evaporates at temperatures above 1,500°C, which has been the main cause of performance degradation. Therefore, the ability to harden the ceramic electrolyte at a lower temperature has been the core issue that determines cell performance.
To solve this, the research team devised a new heat-treatment method called “vapor-phase diffusion.” This technique places a special auxiliary material (a vapor source) next to the cell and irradiates it with microwaves to quickly diffuse vapor. When the temperature reaches approximately 800°C, the vapor released from the auxiliary material moves toward the electrolyte and tightly bonds the ceramic particles. Thanks to this technology, a process that previously required 1,500°C can now be completed at just 980°C. In other words, a world-first ceramic electrochemical cell fabrication technology has been created that produces high-performance electricity at a “low temperature” without damaging the electrolyte.
A cell fabricated with this process produced 2 W of power stably from a 1 cm² cell (roughly the size of a fingernail) at 600°C and generated 205 mL of hydrogen per hour at 600°C (about the volume of a small paper cup, among the highest in the industry). It also maintained stability without performance degradation during 500 hours of continuous operation.
In other words, this technology reduces the production temperature (−500°C), lowers the operating temperature (600°C), doubles performance (2 W/cm²), and extends the lifespan (500-hour stability), achieving world-class performance in ceramic cell technology.
The research team also enhanced the reliability of the technology by using digital twins (virtual simulations) to analyze gas-transport phenomena occurring in the microscopic internal structure of the cell − phenomena that are difficult to observe in actual experiments.
<Figure 1. (a) Schematic of the vapor-diffusion-based process; (b) Surface microstructure of the electrolyte; (c) Internal barium composition ratio of the electrolyte according to processing conditions; (d) Comparison of power-generation performance with previous studies>
< Figure 2. (a) Three-dimensional reconstructed image of the protonic ceramic electrochemical cell fuel electrode according to processing conditions (b) Pore structure (c) Gas-transport simulation results >
Professor Kang Taek Lee emphasized, “This study is the world’s first case of using vapor to lower the heat-treatment temperature by more than 500°C while still producing a high-performance, high-stability cell.” He added, “It is expected to become a key manufacturing technology that addresses the power challenges of the AI era and accelerates the hydrogen society.”
Dongyeon Kim (KAIST PhD) and Yejin Kang (KAIST PhD candidate) participated as co–first authors. The research results were published in Advanced Materials (IF: 26.8), one of the world’s leading journals in energy and materials science, and were selected as the Inside Front Cover article on October 29.
(Paper title: “Sub-1000°C Sintering of Protonic Ceramic Electrochemical Cells via Microwave-Driven Vapor Phase Diffusion,” DOI: https://doi.org/10.1002/adma.202506905)
This research was supported by the MSIT’s Mid-career Researcher Program and the H2 Next Round Program.
2025.12.05 View 1741 -
Highly Efficient and Stable Double Layer Solar Cell Developed
Solar cells convert light into energy, but they can be inefficient and vulnerable to the environment, degrading with, ironically, too much light or other factors, including moisture and low temperature. An international research team has developed a new type of solar cell that can both withstand environmental hazards and is 26.7% efficient in power conversion.
They published their results on March 26 in Science.
The researchers, led by Byungha Shin, a professor from the Department of Materials Science and Engineering at KAIST, focused on developing a new class of light-absorbing material, called a wide bandgap perovskite. The material has a highly effective crystal structure that can process the power needs, but it can become problematic when exposed to environmental hazards, such as moisture. Researchers have made some progress increasing the efficiency of solar cells based on perovskite, but the material has greater potential than what was previously achieved.
To achieve better performance, Shin and his team built a double layer solar cell, called tandem, in which two or more light absorbers are stacked together to better utilize solar energy. To use perovskite in these tandem devices, the scientists modified the material’s optical property, which allows it to absorb a wider range of solar energy. Without the adjustment, the material is not as useful in achieving high performing tandem solar cells. The modification of the optical property of perovskite, however, comes with a penalty — the material becomes hugely vulnerable to the environment, in particular, to light.
To counteract the wide bandgap perovskite’s delicate nature, the researchers engineered combinations of molecules composing a two-dimensional layer in the perovskite, stabilizing the solar cells.
“We developed a high-quality wide bandgap perovskite material and, in combination with silicon solar cells, achieved world-class perovskite-silicon tandem cells,” Shin said.
The development was only possible due to the engineering method, in which the mixing ratio of the molecules building the two-dimensional layer are carefully controlled. In this case, the perovskite material not only improved efficiency of the resulting solar cell but also gained durability, retaining 80% of its initial power conversion capability even after 1,000 hours of continuous illumination. This is the first time such a high efficiency has been achieved with a wide bandgap perovskite single layer alone, according to Shin.
“Such high-efficiency wide bandgap perovskite is an essential technology for achieving ultra-high efficiency of perovskite-silicon tandem (double layer) solar cells,” Shin said. “The results also show the importance of bandgap matching of upper and lower cells in these tandem solar cells.”
The researchers, having stabilized the wide bandgap perovskite material, are now focused on developing even more efficient tandem solar cells that are expected to have more than 30% of power conversion efficiency, something that no one has achieved yet,
“Our ultimate goal is to develop ultra-high-efficiency tandem solar cells that contribute to the increase of shared solar energy among all energy sources,” Shin said. “We want to contribute to making the planet healthier.”
This work was supported by the National Research Foundation of Korea, the Korea Institute of Energy Technology Evaluation and Planning, the Ministry of Trade Industry and Energy of Korea, and the U.S. Department of Energy.
Other contributors include Daehan Kim, Jekyung Kim, Passarut Boonmongkolras, Seong Ryul Pae and Minkyu Kim, all of whom affiliated with the Department of Materials Science and Engineering at KAIST. Other authors include Byron W. Larson, Sean P. Dunfield, Chuanxiao Xiao, Jinhui Tong, Fei Zhang, Joseph J. Berry, Kai Zhu and Dong Hoe Kim, all of who are affiliated with the National Renewable Energy Laboratory in Colorado. Dunfield is also affiliated with the Materials Science and Engineering Program at the University of Colorado; Berry is also affiliated with the Department of Physics and the Renewable and Sustainable Energy Institute at the University of Colorado Boulder; and Kim is also affiliated with the Department of Nanotechnology and Advanced Materials Engineering at Sejong University. Hee Joon Jung and Vinayak Dravid of the Department of Materials Science and Engineering at Northwestern University; Ik Jae Park, Su Geun Ji and Jin Young Kim of the Department of Materials Science and Engineering at Seoul National University; and Seok Beom Kang of the Department of Nanotechnology and Advanced Materials Engineering of Sejong University also contributed.
Image credit: Professor Byungha Shin, KAIST
Image usage restrictions: News organizations may use or redistribute this image, with proper attribution, as part of news coverage of this paper only.
Publication: Kim et al. (2020) “Efficient, stable silicon tandem cells enabled by anion-engineered wide band gap perovskites”. Science. Available online at https://doi.org/10.1126/science.aba3433
Profile:
Byungha Shin
Professor
byungha@kaist.ac.kr
http://energymatlab.kaist.ac.kr/
Department of Materials Science and Engineering
KAIST
Profile:
Daehan Kim
Ph.D. Candidate
zxzx4592@kaist.ac.kr
http://energymatlab.kaist.ac.kr/
Department of Materials Science and Engineering
KAIST
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2020.03.27 View 30452 -
Professor Ilkwon Oh Receives the Energy Technology Innovation Award
Professor Ilkwon Oh from the Division of Ocean Systems Engineering at the School of Mechanical and Aerospace Engineering, KAIST, received the Energy Technology Innovation Award at the Energy Tech Insight 2014 Conference, which was held on August 28, 2014 at COEX in Seoul. The conference was co-hosted by the Ministry of Trade, Industry & Energy, Republic of Korea, and the Korea Institute of Energy Technology Evaluation and Planning.
Professor Oh has been recognized for his distinguished research on a synthetic technology to develop 3-dimensional carbon nanostructures based on defect engineering and for his efforts to apply this technology to produce cathode materials for high performance, high density lithium-ion secondary batteries.
In 2010, the Ministry of Education, the Republic of Korea, and the National Research Foundation of Korea included Professor Oh's research in the 100 Best Research in Basic Sciences of the Year, and the 50 Best Research in Basic Sciences in 2012 and 2014, respectively.
2014.09.07 View 12115