First Instance of Negative Effects from Terahertz-Range Electromagnetic Waves
Professor Philhan Kim
Electromagnetic waves (EM-wave) in the terahertz range were widely regarded as the “dream wavelength” due to its perceived neutrality. Its application was also wider than X-rays. However, KAIST scientists have discovered negative effects from terahertz EM-waves.
Professor Philhan Kim of KAIST’s Graduate School of Nanoscience and Technology and Dr. Young-wook Jeong of the Korea Atomic Energy Research Institute (KAERI) observed inflammation of animal skin tissue when exposed to terahertz EM-waves.
The results were published in the online edition of Optics Express (May 19, 20104).
Terahertz waves range from 0.1 to 10 terahertz and have a longer wavelength than visible or infrared light. Commonly used to see through objects like the X-ray, it was believed that the low energy of terahertz waves did not inflict any harm on the human body.
Despite being applied for security checks, next-generation wireless communications, and medical imaging technology, little research has been conducted in proving its safety and impact. Conventional research failed to predict the exact impact of terahertz waves on organic tissues as only artificially cultured cells were used.
The research team at KAERI developed a high power terahertz EM-wave generator that can be used on live organisms. A high power generator was necessary in applications such as biosensors and required up to 10 times greater power than currently used telecommunications EM-wave. Simultaneously, a KAIST research team developed a high speed, high resolution video-laser microscope that can distinguish cells within the organism.
The experiment exposed 30 minutes of terahertz EM-wave on genetically modified mice and found six times the normal number of inflammation cells in the skin tissue after six hours. It was the first instance where negative side effects of terahertz EM-wave were observed.
Professor Kim commented that “the research has set a standard for how we can use the terahertz EM-wave safely” and that “we will use this research to analyze and understand the effects of other EM-waves on organisms.”
An Electron Cloud Distribution Observed by the Scanning Seebeck Microscope
All matters are made of small particles, namely atoms. An atom is composed of a heavy nucleus and cloud-like, extremely light electrons.
Korean researchers developed an electron microscopy technique that enables the accurate observation of an electron cloud distribution at room-temperature. The achievement is comparable to the invention of the quantum tunneling microscopy technique developed 33 years ago.
Professor Yong-Hyun Kim of the Graduate School of Nanoscience and Technology at KAIST and Dr. Ho-Gi Yeo of the Korea Research Institute of Standards and Science (KRISS) developed the Scanning Seebeck Microscope (SSM). The SSM renders clear images of atoms, as well as an electron cloud distribution. This was achieved by creating a voltage difference via a temperature gradient.
The development was introduced in the online edition of Physical Review Letters (April 2014), a prestigious journal published by the American Institute of Physics.
The SSM is expected to be economically competitive as it gives high resolution images at an atomic scale even for graphene and semiconductors, both at room temperature. In addition, if the SSM is applied to thermoelectric material research, it will contribute to the development of high-efficiency thermoelectric materials.
Through numerous hypotheses and experiments, scientists now believe that there exists an electron cloud surrounding a nucleus. IBM's Scanning Tunneling Microscope (STM) was the first to observe the electron cloud and has remained as the only technique to this day. The developers of IBM microscope, Dr. Gerd Binnig and Dr. Heinrich Rohrer, were awarded the 1986 Nobel Prize in Physics.
There still remains a downside to the STM technique, however: it required high precision and extreme low temperature and vibration. The application of voltage also affects the electron cloud, resulting in a distorted image.
The KAIST research team adopted a different approach by using the Seebeck effect which refers to the voltage generation due to a temperature gradient between two materials.
The team placed an observation sample (graphene) at room temperature (37~57℃) and detected its voltage generation. This technique made it possible to observe an electron cloud at room temperature.
Furthermore, the research team investigated the theoretical quantum mechanics behind the electron cloud using the observation gained through the Seebeck effect and also obtained by simulation capability to analyze the experimental results.
The research was a joint research project between KAIST Professor Yong-Hyun Kim and KRISS researcher Dr. Ho-Gi Yeo. Eui-Seop Lee, a Ph.D. candidate of KAIST, and KRISS researcher Dr. Sang-Hui Cho also participated. The Ministry of Science, ICT, and Future Planning, the Global Frontier Initiative, and the Disruptive Convergent Technology Development Initiative funded the project in Korea.
Picture 1: Schematic Diagram of the Scanning Seebeck Microscope (SSM)
Picture 2: Electron cloud distribution observed by SSM at room temperature
Picture 3: Professor Yong-Hyun Kim
Dopant properties of silicon nanowires investigated
Professor Chang Kee Joo
Professor Kee Joo Chang’s research team from the Department of Physics at KAIST has successfully unearthed the properties of boron and phosphorous dopants in silicon nanowires, a material expected to be used in next generation semiconductors. The research team was the first in the world to investigate the movement of boron and phosphorous (impurities or ‘dopants’ added for electrical flow) in oxidized silicon nanowires and study the mechanism behind its deactivation.
It is nearly impossible to develop a silicon based semiconductor thinner than 10nm, even using the most advanced modern technology. However, the thickness of silicon nanowires are within the nano level and hence, allows a higher degree of integration in semiconductors.
For silicon nanowires to carry electricity, small amounts of boron and phosphorous need to be added (‘doping’ process). Compared to silicon, nanowires are harder to create due to the difficulties in the doping process as well as the control of electrical conduction properties.
Professor Chang’s research team improved upon the existing simple model by applying revolutionary quantum simulation theory to create a realistic core-shell atomic model. This research successfully investigated the cause of the escape of boron dopants from the silicon core during oxidation. It was also found that although phosphorous dopants do not escape as oxides, they form electrically deactivated pairs which decreases the efficiency. These phenomena were attributed to the film shape of the nano-wires, which increases the relative surface area compared to a same volume of silicon.
The research results were published in the online September edition of the world renowned Nano Letters.
Figure: The longitudinal section diagram of the Silicon/oxide core-shell model
New Text Book on Chemistry Published by KAIST Professor and Student
A chemistry textbook written in English and Korean will aid Korean students to learn General Chemistry in a global academic setting.
Korean students majoring in chemistry and looking for an opportunity to study abroad will have a new, handy textbook that presents them with a practical introduction to an English speaking lecture on general chemistry.
Aiming for advanced Korean high school and college/university students, the inter-language textbook is written by two incumbent professors teaching chemistry at a university in Korea and the US. The book will help Korean students prepare for a classroom where various topics of general chemistry are presented and discussed in English. Clear, collated sections of English and Korean text provide the student with sufficient explanation of the rudimentary topics and concepts.
Composed of 15 chapters on the core subjects of General Chemistry, i.e., Stoichiometry and Chemical Reactions, Thermochemistry, Atomic Structure, and Bonding, the textbook includes essential English vocabulary and usage sections for each chapter; it also contains a pre-reading study guide on the subject that prepares the student for listening to a lecture. This section includes view-graph type slides, audio files, and follow-up questions the student can use to prepare for an English-speaking course. The various accompanying audio files are prepared to expose the student to English scientific dialogue and serve as examples for instruction at Korean secondary and tertiary schools.
The book was coauthored by Korean and American scientists: A father and son, who have taught chemistry at an American and Korean university, wrote the book. Professor Melvyn R. Churchill at the State University of New York at Buffalo and Professor David G. Churchill at KAIST prepared all of the technical English text which was adapted from General Chemistry course lecture notes; the text was further shaped by original perspectives arising from many student interactions and questions.
This English text was translated into Korean by Professor Kwanhee Lee from the Department of Life and Food Science at Handong Global University, who coauthored a previous preparatory book for Korean students in a different subject. He also supplied an important introductory section which serves as a general guide to the classroom student. Kibong Kim, a doctoral student in the Department of Chemistry at KAIST, helped in preparing the book as well.
“This has been definitely a collaborative undertaking with an international academic crew and it underscores that the Korean internationalization in science is mainstream. Professors and a Korean student created a new book for Korean consumption and benefit,” Professor David G. Churchill says.
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Bibliography: “How to Prepare for General Chemistry Taught in English” by David George Churchill, Melvyn Rowen Churchill, Kwanhee Lee & Kibong Kim, Darakwon Publishing, Paju, Republic of Korea, 2010, 400 pp, ISBN 978-89-5995-730-9 (1 Audio CD included)
Storing Stably Hydrogen Atoms in Icy Materials Discovered
KAIST, Aug. 8, 2008 -- A KAIST research team led by Prof. Huen Lee of the Department of Chemical & Biomolecular Engineering has discovered that icy organic hydrates, which contain small cages that can trap guest molecules, can be used to create and trap hydrogen atoms at higher temperatures.
The properties and reactions of single hydrogen atoms are of great scientific interest because of their inherent quantum mechanical behavior; experimentally, they can be generated and stabilized at very low temperatures (4 K) by high-energy irradiation of solid molecular hydrogen.
The finding was reported in the journal of American Chemical Society and featured in the "Editor"s Choice" in the July 11 issue of Science as a recent research highlight.
Hydrogen is a clean and sustainable form of energy that can be used in mobile and stationary applications. Hydrogen has the potential to solve several major challenges today: depletion of fossil fuels, poor air quality, and green house gas emissions.
However, the trapping of hydrogen atoms in crystalline solid matrix has never been attempted mainly because of experimental difficulties in identifying the generated hydrogen atoms with either spectroscopic or microscopic technique.
"To overcome the barriers and limitations of the existing storage approaches, we have continuously attempted to find the new hydrogen storage media such as icy powders and other related inclusion compounds," said Prof. Lee
The discovery follows the breakthrough concept Prof. Lee"s research team proposed in Nature in 2005 to use pure ice to capture and store hydrogen molecules. At moderate temperature and pressure conditions small guest molecules are entrapped in pure ice powders to form the mixed icy hydrate materials.
"Stable existence of single hydrogen molecule/radical in icy crystalline matrices may offer significant advantages in exploring hydrogen as a quantum medium because icy hydrogen hydrates can be formed at milder conditions when compared with pure solid hydrogen, which requires the ultra low temperature of 4.2 K," said Prof. Lee.
The novel design and synthesis of ionic and radicalized icy hydrates are expected to open a new field for inclusion chemistry and ice-based science and technology. Specifically, the fact that hydrogen atoms can be stably stored in icy materials might provide versatile and practical applications to energy devices including fuel cells, ice-induced reactions, and novel energy storage process, according to the KAIST professor.